Epoxy KTL Coating for PU-Metal Bonding in Damping Elements

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Solution Overview

Problem

Current damping elements, particularly those with hybrid systems of plastic and metal components, face limitations due to insufficient bonding between plastic and metal elements, leading to adhesive detachment under tensile shear forces, which complicates production and increases costs.

Innovation Solution

A composite element comprising a metallic body with an epoxy resin coating and a polyurethane enclosure, where the epoxy resin acts as both a corrosion protection and adhesion promoter, eliminating the need for additional adhesion promoters and simplifying the production process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If an electroplated zinc-iron or zinc-nickel coating is applied for corrosion protection, then corrosion resistance is improved, but adhesion between plastic and metal is insufficient leading to adhesive detachment

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidadhesion strength
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent combines corrosion protection and adhesion promotion into a single coating layer. The epoxy resin coating is applied over the electroplated zinc-iron or zinc-nickel layer, merging the protective function of the metal coating with the adhesive function of the epoxy resin, thereby eliminating adhesive detachment while maintaining corrosion resistance

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The epoxy resin coating acts as an intermediary layer between the electroplated metal coating and the plastic body. This intermediate layer provides the necessary adhesion strength to prevent detachment while allowing the underlying metal coating to maintain its corrosion protection function

Inventive Principle:
Principle #24Intermediary (Mediator)

2Strength

If a standard wet-chemical adhesion promoter is applied to the corrosion protection layer, then adhesion is improved, but manufacturing complexity and costs increase

Engineering Contradiction:
Improveadhesion strengthVSAvoidmanufacturing process complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent merges the adhesion promoter function with the corrosion protection coating by applying the epoxy resin coating directly over the electroplated layer. This eliminates the need for a separate adhesion promoter application step, reducing manufacturing complexity while maintaining strong adhesion

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The epoxy resin coating serves multiple functions simultaneously: it provides adhesion promotion for the plastic body, maintains corrosion protection by sealing the metal coating, and can be applied in a single step using cathodic dip coating, thereby reducing the number of process steps

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Strength

If an adhesion promoter is applied partially to keep screw-on surfaces clear, then adhesion is maintained, but the application process becomes complex and expensive

Engineering Contradiction:
Improveadhesion strengthVSAvoidease of manufacture
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The epoxy resin coating provides universal coverage across the entire metal component surface, including areas with screw-on surfaces. The coating formulation and application process are designed to accommodate threaded surfaces without requiring selective masking or partial application, thereby simplifying manufacturing

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent modifies the coating application parameters by using cathodic dip coating, which allows the coating to be applied uniformly across complex geometries including threaded surfaces. This electrochemical application method changes the deposition parameters to achieve complete coverage without the need for selective application

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The epoxy resin coating enhances adhesion between plastic and metal bodies, improving the load-bearing capacity of damping elements while reducing production costs and complexity, and can be applied economically using methods like dipping.

Implementation Method 1

The epoxy resin acts as both a corrosion protection and adhesion promoter, eliminating the need for additional adhesion promoters

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

a composite element has a conversion layer (d) between the surface of the metallic body (a) and the coating (b), which comprises at least one compound selected from the group consisting of zirconium(IV) oxide, zinc(II) phosphate and chromate

Methodology Applied
Scientific EffectChemisorption: Chemisorption

Data Source

PatentEP3790917B1Epoxy resin based cathodic dip coating (KTL) of metal components as adhesion promoters for pu systems
Publication Date: 2023.08.02 BASF POLYURETHANES
  • EP3790917B1 patent drawingFigure 1~2
  • EP3790917B1 patent drawingFigure 3~4
  • EP3790917B1 patent drawingFigure 5~6

AI summary

The present invention relates to a composite element, in particular for a damping element, comprising: a) at least one metal body having an upper surface; b) a coating comprising an epoxy resin on at least one portion of the surface of the metal body; c) a plastic body comprising at least one polyurethane which encloses at least part of the metal body according to (a) and at least part of which, in the region of said enclosure, is in direct contact with the coating according to (b), wherein the composite element has a conversion coating (d) between the surface of the metal body (a) and the coating (b), said conversion coating comprising at least one compound selected from the group consisting of zirconium(IV) oxide, zinc(II) phosphate, and chromate. The invention also relates to a damping element comprising the composite element and at least one additional body, at least part of which is in direct contact with the composite element, preferably with the plastic body according to (c). The invention also relates to manufacturing methods for the composite element and the damping element, the composite or damping elements which are manufactured or can be manufactured according to said method, and the use of said composite or damping elements.