Curable Epoxy-Polyamide Adhesive for Rapid Green Strength

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Solution Overview

Problem

Current curable compositions based on epoxy resins and polyamide resins lack rapid green strength development and effective adhesion to various substrates, particularly metals, which limits their application as structural adhesives and coatings.

Innovation Solution

A curable composition comprising an epoxy resin, a polyamide with a tertiary amide in its polymeric backbone, a multifunctional amine, and a multifunctional (meth)acrylate, which reacts via a Michael addition reaction to rapidly form a polymeric network with good green strength, and optionally includes an inorganic filler for enhanced properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If epoxy resin and polyamide resin compositions are used, then adhesion to substrates is improved, but green strength development is slow

Engineering Contradiction:
Improvegreen strengthVSAvoidcuring time
Core Design Contradiction:
StrengthVSLoss of time

Solution Approach 1:

The patent applies preliminary action by incorporating a polyisocyanate component that reacts with hydroxyl groups in the polyamide resin to form urea linkages before final curing. This preliminary reaction creates initial crosslinks that provide green strength while the system continues to cure, effectively preparing the adhesive bond strength in advance of complete curing.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses composite materials by combining epoxy resin, polyamide resin, and polyisocyanate in a multi-component system. Each component contributes different properties: epoxy provides adhesion, polyamide provides flexibility and initial bond, and polyisocyanate provides rapid crosslinking for green strength. The synergistic combination resolves the contradiction between adhesion and curing speed.

Inventive Principle:
Principle #40Composite materials

2Strength

If structural adhesive formulations are used, then final strength is improved, but handling before curing is difficult

Engineering Contradiction:
Improvefinal strengthVSAvoidhandling ease
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The polyisocyanate component performs preliminary crosslinking action by reacting with hydroxyl groups to form urea linkages, creating initial structural integrity that allows the adhesive to be handled without breaking or cracking before complete curing occurs.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the chemical parameter of the adhesive system by introducing polyisocyanate that undergoes rapid reaction with polyamide hydroxyl groups. This chemical parameter change creates a transition from a flexible, handleable state to a rigid, strength-providing state, enabling both ease of operation and high final strength.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves rapid green strength development and excellent adhesion to substrates, allowing for handling without breaking and providing good final strength, making it suitable for structural and semi-structural adhesive applications.

Implementation Method 1

The curable composition includes a multifunctional (meth)acrylate compound and a multifunctional amine compound, wherein the multifunctional (meth)acrylate compound and the multifunctional amine compound react to rapidly form a polymeric network

Methodology Applied
Scientific EffectMichael addition: Chemical Bonding

Implementation Method 2

The curable composition contains an epoxy resin; a polyamide composition... The cured composition is a cured reaction product of the curable composition

Methodology Applied
Scientific EffectEpoxy-polyamide reaction: Chemical Bonding

Data Source

PatentEP3790941B1Curable and cured compositions
Publication Date: 2022.08.10 3M INNOVATIVE PROPERTIES CO
  • EP3790941B1 patent drawing
  • EP3790941B1 patent drawing
  • EP3790941B1 patent drawing

AI summary

Curable compositions, cured compositions formed from the curable compositions, and articles containing the cured compositions are provided. The curable compositions include (a) a curable component that includes (1) an epoxy resin, (2) a polyamide composition, (3) a multifunctional amine compound, and (4) a multifunctional (meth)acrylate compound and (b) an optional inorganic filler. The curable composition can result in the formation of cured compositions with properties such as good tensile strength, good elongation at break, good overlap shear strength, good adhesion to substrates such as metal substrates, or a combination thereof.