Epoxy Casting Resin Formulation for Water-Resistant Cable Joint Insulation

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Solution Overview

Problem

Current polyurethane casting resins used for electrical insulation of cable joints are sensitive to water, leading to foaming issues and health concerns due to isocyanate-based hardeners, and face challenges with temperature variations affecting curing time, which can result in insufficient insulation and costly repairs.

Innovation Solution

A curable two-component epoxy resin precursor system comprising an epoxy resin, amine-based epoxy curing agents, mineral filler, phenolic lipid, and triphenylmethane dye, which provides improved handling, mechanical, and electrical properties, including resistance to water and reduced exothermic heat, allowing for reliable on-site insulation of cable joints.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If polyurethane casting resins with isocyanate-based hardeners are used for cable joint insulation, then the resins exhibit low viscosity and fast curing, but the resins are sensitive to water causing foaming and present health concerns

Engineering Contradiction:
Improveviscosity and curing speedVSAvoidwater sensitivity and foaming
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters by replacing isocyanate-based hardeners with amine-based epoxy curing agents. This fundamental parameter change eliminates water sensitivity and foaming while maintaining low viscosity and fast curing properties through careful selection of epoxy resin and curing agent ratios

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite material formulation combining epoxy resin with amine-based curing agents, mineral fillers, and phenolic lipids. This composite approach creates a resin system that integrates multiple beneficial properties: water resistance from epoxy chemistry, controlled viscosity from resin composition, and fast curing from amine catalysts

Inventive Principle:
Principle #40Composite materials

2Reliability

If polyurethane casting resins are modified to increase hydrophobicity, then the resins can cure in the presence of water, but foaming may still occur under certain circumstances

Engineering Contradiction:
Improvecuring capability in presence of waterVSAvoidfoaming
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts the problematic isocyanate component from the resin system and replaces it with epoxy resin and amine-based curing agents. This removal of the water-reactive isocyanate eliminates the source of foaming while maintaining the ability to cure in humid conditions through the epoxy-amine reaction mechanism

Inventive Principle:
Principle #2Taking out (Extraction)

3Reliability

If isocyanate-based hardeners are used in casting resins, then the resins achieve suitable curing properties, but health and safety concerns arise due to carcinogenic properties

Engineering Contradiction:
Improvecuring propertiesVSAvoidcarcinogenicity
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent converts the harmful isocyanate chemistry into beneficial epoxy-amine chemistry. The amine-based curing agents provide effective curing properties while being significantly safer for human health and environmental compatibility, transforming a hazardous system into a safe one

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Adaptability or versatility

If temperature variations occur on construction sites, then curing time becomes difficult to predict, but cable joints must remain stationary until fully cured

Engineering Contradiction:
Improvecuring time flexibilityVSAvoidcuring completion certainty
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The patent incorporates visual indicators that provide real-time feedback on the curing progress. This allows workers to monitor the curing state directly and determine when the joint is ready for movement, eliminating the need to rely solely on temperature-based time predictions and providing clear visual confirmation of curing completion

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The epoxy resin system offers enhanced shelf-life, easy mixing and pouring, resistance to water, reduced thermal damage, and visual monitoring of mixing and curing, ensuring effective electrical insulation and mechanical protection of cable joints without foaming or health hazards.

Implementation Method 1

at least one of part (A) and part (B) comprises at least one triphenylmethane dye

Methodology Applied
Scientific EffectColor change indication:

Implementation Method 2

a first part (A) comprising: at least one epoxy resin; a second part (B) comprising: at least one first amine-based epoxy curing agent

Methodology Applied
Scientific EffectEpoxy-amine curing reaction: Chemical Bonding

Implementation Method 3

reduced generation of exothermic heat

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Data Source

PatentUS11732155B2Epoxy casting resin formulation
Publication Date: 2023.08.22 3M INNOVATIVE PROPERTIES CO
  • US11732155B2 patent drawing
  • US11732155B2 patent drawing

AI summary

The present disclosure provides a curable casting resin precursor, comprising (a) a first part (A) comprising: (a1) at least one epoxy resin; (b) a second part (B) comprising: (b1) at least one first amine-based epoxy curing agent; (b2) optionally, at least one second amine-based epoxy curing agent; (b3) at least one mineral filler; (b4) at least one phenolic lipid; wherein part (A) and/or part (B) comprise at least one triphenylmethane dye. The curable casting resin precursor is suited for encapsulating metal parts such as cable joints and the like.