Epoxy Resin Composition Viscosity Control for Prepregs

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Solution Overview

Problem

Existing epoxy resin compositions for prepregs face challenges with viscosity adjustment, leading to resin flow during curing, resulting in resin loss and uneven thickness, while high viscosity at room temperature compromises workability.

Innovation Solution

Incorporating a curing agent, silica microparticles, and core-shell rubber particles in specific blended amounts and ratios within the epoxy resin composition to control viscosity and prevent resin flow during heat curing, maintaining workability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If the viscosity of the resin composition is increased to suppress resin flow during curing, then resin loss and thickness unevenness are reduced, but the workability during prepreg formation deteriorates due to excessively high viscosity at room temperature

Engineering Contradiction:
Improvethickness uniformityVSAvoidworkability
Core Design Contradiction:
Manufacturing precisionVSEase of operation

Solution Approach 1:

The patent applies parameter changes by modifying the chemical composition parameters of the resin system. Specifically, it changes the epoxy resin type (using low-viscosity variants), adjusts the curing agent selection and ratio, and optimizes the filler particle size distribution. These parameter modifications enable the resin to maintain appropriate viscosity at room temperature for good workability while developing higher viscosity at curing temperature to suppress resin flow and ensure thickness uniformity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by creating a multi-component resin system that combines epoxy resin with specific curing agents and fillers. This composite approach allows the system to exhibit different rheological properties at different temperatures - the combination of components works synergistically to provide low viscosity at room temperature for ease of handling while achieving high viscosity during curing to prevent resin loss and maintain thickness uniformity.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If a thermoplastic resin is added for viscosity adjustment, then the viscosity can be controlled, but the resin composition becomes more complex and may affect the curing characteristics

Engineering Contradiction:
Improveviscosity controlVSAvoidcomposition complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

Rather than adding thermoplastic resins, the patent uses parameter changes within the epoxy-curing agent-filler system to achieve viscosity control. By adjusting the epoxy resin molecular weight, curing agent type and proportion, and filler characteristics, the patent achieves effective viscosity management without introducing additional resin types, thereby maintaining composition simplicity while avoiding interference with curing characteristics.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the resin composition flows out from the reinforcing fiber during heating and curing, then the curing process is complete, but resin loss occurs and the thickness becomes uneven

Engineering Contradiction:
Improvecuring completionVSAvoidresin loss
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The patent uses parameter changes to achieve controlled resin viscosity during curing. By selecting specific epoxy resin types with appropriate molecular weights, optimizing the curing agent ratio, and adjusting filler content and particle size, the resin system achieves sufficiently high viscosity at curing temperature to prevent excessive flow and resin loss while still allowing complete curing to occur. This parameter optimization ensures both curing completion and thickness uniformity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent references and builds upon known resin systems and curing formulations, adapting proven compositions to achieve the desired viscosity characteristics. By copying successful formulations from prior art and making targeted adjustments to resin type, curing agent selection, and filler properties, the patent achieves reliable curing completion without the resin loss and thickness unevenness problems associated with conventional compositions.

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively suppresses resin flow and thickness unevenness during curing, ensuring excellent workability and mechanical strength of the resulting fiber-reinforced composite materials.

Implementation Method 1

blending a curing agent or a curing accelerator, silica microparticles, and core-shell rubber particles in an epoxy resin and specifying blended amounts of the silica microparticles and the core-shell rubber particles

Methodology Applied
Scientific EffectViscosity adjustment through particle blending:

Implementation Method 2

a curing agent or a curing accelerator... in an epoxy resin

Methodology Applied
Scientific EffectCuring reaction: Chemical Bonding

Data Source

PatentUS20230133111A1Epoxy resin composition for prepreg, and prepreg
Publication Date: 2023.05.04 THE YOKOHAMA RUBBER CO LTD

AI summary

The epoxy resin composition for a prepreg according to an embodiment of the present invention contains (A) an epoxy resin, (B) a curing agent or a curing accelerator, (C) silica microparticles, and (D) core-shell rubber particles, the epoxy resin composition containing from 1 to 5 parts by mass of (C) the silica microparticles and from 2 to 10 parts by mass of (D) the core-shell rubber particles per 100 parts by mass of (A) the epoxy resin, and a mass ratio of (C) the silica microparticles to (D) the core-shell rubber particles, in terms of (C)/(D), being from 1/1 to 1/5.