Epoxy-Modified Resist Composition for Adhesion and Pattern Collapse

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Solution Overview

Problem

Current resist materials face challenges in achieving excellent adhesion to substrates and preventing pattern collapse during the formation of resist patterns, especially in applications involving thick films and miniaturized patterns, where existing methods increase process complexity and do not adequately improve adhesion or lithography properties.

Innovation Solution

A resist composition comprising a base component that changes solubility in an alkali developing solution under acid action, combined with an epoxy resin, which generates acid upon exposure to form a resist film with enhanced adhesion and reduce pattern collapse.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional resist materials and methods are used, then the resist pattern formation process is simple, but adhesion to substrates is insufficient and pattern collapse occurs

Engineering Contradiction:
Improveadhesion to substrateVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines the base resin and epoxy resin into a single resist composition formulation, merging the adhesion function (epoxy) with the lithography function (base resin) into one integrated material system, eliminating the need for separate adhesion treatment steps

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The epoxy resin serves multiple functions simultaneously: it provides adhesion to the substrate, prevents pattern collapse, and maintains lithography performance, making the resist composition universally applicable for thick film and miniaturized pattern applications without requiring additional process steps

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Volume of moving object

If thick films are used, then the resist film has sufficient coverage, but pattern collapse occurs

Engineering Contradiction:
Improveresist film thicknessVSAvoidpattern stability
Core Design Contradiction:
Volume of moving objectVSReliability

Solution Approach 1:

The patent creates a composite resist material system combining base resin and epoxy resin, where the epoxy component provides structural support and adhesion that prevents pattern collapse in thick film applications while maintaining the necessary film coverage

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If miniaturized patterns are formed, then the resolution is improved, but pattern collapse increases

Engineering Contradiction:
Improvepattern resolutionVSAvoidpattern stability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The epoxy resin provides localized adhesion and structural support at the pattern interfaces and critical regions, strengthening where needed to prevent collapse of miniaturized features while maintaining the high resolution achieved through lithography

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resist composition achieves excellent adhesion to substrates and suppresses pattern collapse, improving the overall lithography performance and simplifying the resist pattern formation process.

Implementation Method 1

an acid generator component (B) that generates acid upon exposure

Methodology Applied
Scientific EffectPhotoacid generation: Photopolymerisation

Implementation Method 2

a base component (A) that exhibits changed solubility in an alkali developing solution under the action of acid

Methodology Applied
Scientific EffectChemical amplification: Chemical Bonding

Implementation Method 3

an epoxy resin (G)... achieves excellent adhesion to substrates

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS8354218B2Resist composition and method of forming resist pattern
Publication Date: 2013.01.15 TOKYO OHKA KOGYO CO LTD
  • US8354218B2 patent drawing
  • US8354218B2 patent drawing
  • US8354218B2 patent drawing

AI summary

A resist composition that includes a base component (A) that exhibits changed solubility in an alkali developing solution under the action of acid, an acid generator component (B) that generates acid upon exposure, and an epoxy resin (G). Also, a method of forming a resist pattern that includes using the above resist composition to form a resist film on the substrate, conducting exposure of the resist film, and alkali-developing the resist film to form a resist pattern.