Epoxy Composition UV Curing Adhesion Strength

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Solution Overview

Problem

Traditional epoxy-based adhesives have a slow curing time, which limits their application, and incorporating acrylate compounds to speed up curing compromises humidity reliability and low shrinkage properties.

Innovation Solution

An epoxy-based composition comprising epoxidized unsaturated polyolefin, thiol compounds, and a curing catalyst, which enables fast curing under UV light and enhances adhesion strength after thermal treatment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional epoxy based adhesive is used, then excellent adhesion strength and chemical stability are achieved, but curing time is slow

Engineering Contradiction:
Improveadhesion strengthVSAvoidcuring time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent uses a composite curing system combining thiol compounds and epoxidized unsaturated polyolefins with epoxy resin. This composite material approach enables dual-curing capability: UV light initiates rapid thiol-epoxide crosslinking for fast initial cure, while thermal energy completes the epoxy polymerization for final strength development, resolving the contradiction between fast curing and strong adhesion

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical parameters of the curing system by introducing thiol compounds with specific functional groups and epoxidized unsaturated polyolefins with controlled epoxy content. This parameter modification allows the system to respond to different energy inputs (UV and heat), achieving both rapid initial cure and complete polymerization for optimal adhesion strength

Inventive Principle:
Principle #35Parameter changes

2Loss of time

If acrylate compounds are incorporated to speed up curing, then curing time is reduced, but humidity reliability and low shrinkage property are damaged

Engineering Contradiction:
Improvecuring timeVSAvoidhumidity reliability
Core Design Contradiction:
Loss of timeVSReliability

Solution Approach 1:

The patent extracts and removes acrylate compounds from the adhesive formulation, replacing them with thiol compounds and epoxidized unsaturated polyolefins. This extraction eliminates the harmful effects of acrylates on humidity reliability and shrinkage properties while achieving fast curing through the thiol-epoxide reaction mechanism

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces thiol compounds as intermediary substances that mediate between UV light energy and the epoxy resin. The thiol groups absorb UV energy and transfer it to initiate rapid crosslinking, serving as a bridge that enables fast curing without requiring acrylate compounds, thus preserving humidity reliability and low shrinkage characteristics

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves rapid UV curing and significantly improves adhesion strength after thermal curing, maintaining humidity reliability and low shrinkage properties without using acrylates.

Implementation Method 1

The epoxy based composition exhibits fast curing property under UV light

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

at least one curing catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

improved adhesion strength after being further heated

Methodology Applied
Scientific EffectThermal curing: Heating

Data Source

PatentUS11390742B2Epoxy based composition
Publication Date: 2022.07.19 HENKEL KGAA
  • US11390742B2 patent drawing
  • US11390742B2 patent drawing

AI summary

This invention relates to an epoxy based composition, comprising at least one epoxidized unsaturated polyolefin; at least one thiol compound; and at least one curing catalyst. The epoxy based composition according to the present invention exhibits fast curing property under UV light and has improved adhesion strength after being further heated.