Erasable Ink Composition With Adjustable Color Erasing Time

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Solution Overview

Problem

Existing erasable inks lack control over the time it takes for the color to be erased.

Innovation Solution

An erasable ink set comprising an erasable ink with a pH indicator and an erasing time adjuster, which includes water and a water-soluble organic solvent or surfactant, allows for controlling the erasing time by adjusting the application of the erasing time adjuster on the recording medium.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If an erasable ink using a pH indicator is used, then the ink can be erased by changing from alkaline to neutral state, but the time until the color is erased cannot be controlled

Engineering Contradiction:
ImproveerasabilityVSAvoiderasing time control
Core Design Contradiction:
Ease of operationVSDuration of action of moving object

Solution Approach 1:

The patent applies parameter changes by modifying the chemical composition parameters of the ink system. Specifically, it adjusts the pH indicator concentration (0.1-3.0 wt%), alkali metal hydroxide concentration (0.1-5.0 wt%), water-soluble organic solvent content (5-50 wt%), and surfactant concentration (0.1-5.0 wt%) to precisely control the erasing time. This allows the erasing time to be adjusted within a specific range (3 hours to 7 days) while maintaining the erasability function.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces an intermediary mechanism by adding a water-soluble organic solvent and/or surfactant that mediates between the pH indicator and the environment. These intermediaries control the rate at which the pH indicator responds to neutralization, thereby controlling the erasing time without affecting the fundamental erasability mechanism.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Stability of the object's composition

If conventional ink formulations are used, then color stability is maintained, but the ability to control erasing time is lost

Engineering Contradiction:
Improvecolor stabilityVSAvoiderasing time
Core Design Contradiction:
Stability of the object's compositionVSDuration of action of moving object

Solution Approach 1:

The patent creates a composite ink formulation by combining multiple components with specific functions: pH indicator (for color change), alkali metal hydroxide (for alkaline state), water-soluble organic solvent (for controlling dissolution rate), and surfactant (for enhancing solubility and controlling interface). This composite structure enables both color stability during storage and controlled erasing time when neutralized.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent systematically adjusts composition parameters to achieve the desired balance between stability and erasability. The pH indicator concentration (0.1-3.0 wt%), alkali metal hydroxide concentration (0.1-5.0 wt%), water-soluble organic solvent content (5-50 wt%), and surfactant concentration (0.1-5.0 wt%) are optimized to ensure color stability while enabling controlled erasing within 3 hours to 7 days.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The erasing time of the erasable ink can be precisely controlled, ranging from under 3 hours to over 7 days, depending on the application of the erasing time adjuster, enhancing the flexibility and effectiveness of the ink's erasing process.

Implementation Method 1

an erasable ink using a pH indicator which develops color in an alkaline state, for example, with phenolphthalein or the like, and erases color in a neutral state

Methodology Applied
Scientific EffectpH indicator color change: Photochromism

Data Source

PatentEP4116383B1Erasable ink set, erasable ink printing apparatus, ink set container, printing method, and printed matter
Publication Date: 2025.11.19 BROTHER KOGYO KK
  • EP4116383B1 patent drawingFigure 1
  • EP4116383B1 patent drawing
  • EP4116383B1 patent drawing

AI summary

An erasable ink set includes: an erasable ink; and an erasing time adjuster that adjusts an erasing time of the erasable ink, wherein the erasable ink includes a color developing agent, water, and at least one of a first water-soluble organic solvent or a first surfactant, the color developing agent includes a pH indicator, and the erasing time adjuster includes water and at least one of a second water-soluble organic solvent or a second surfactant.