Electrostatic Chuck Protrusions Using Hydrogen-Free Amorphous Carbon

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Solution Overview

Problem

Existing electrostatic chucks (ESCs) in semiconductor manufacturing suffer from protrusions that are prone to fall off at high temperatures due to poor high-temperature resistance and generate particles that attach to wafers, impacting the manufacturing process.

Innovation Solution

The ESC features protrusions made of hydrogen-free amorphous carbon with resistivity ranging from 10−4 Ω·cm to 10^9 Ω·cm, supported by an adhesive layer of metals like titanium or chromium, which are deposited using carbon plasma and a magnetic field to ensure high hardness, wear resistance, and conductivity, preventing particle attachment and maintaining stability up to 500°C.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If protrusions are formed on the ESC surface to reduce particle attachment, then particle generation is reduced, but the protrusions are prone to fall off due to poor high-temperature resistance

Engineering Contradiction:
Improveparticle generationVSAvoidprotrusion stability
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The invention uses hydrogen-free amorphous carbon as the protrusion material, which combines high hardness, wear resistance, and high-temperature stability. This composite material structure maintains protrusion integrity at high temperatures while continuing to reduce particle generation during wafer processing.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention controls the resistivity of hydrogen-free amorphous carbon within a specific range (10^-4 to 10^9 Ω·cm) to optimize both the electrical functionality and thermal stability of the protrusions. By adjusting material parameters, the protrusions maintain stability at high temperatures while preserving their electrostatic function.

Inventive Principle:
Principle #35Parameter changes

2Object-generated harmful factors

If existing protrusions are used, then particle attachment is reduced, but they cannot withstand high-temperature environments

Engineering Contradiction:
Improveparticle attachmentVSAvoidhigh-temperature resistance
Core Design Contradiction:
Object-generated harmful factorsVSTemperature

Solution Approach 1:

Hydrogen-free amorphous carbon provides a composite material solution that simultaneously delivers low particle attachment and high-temperature resistance. The unique atomic structure of this material prevents thermal degradation while maintaining surface properties that minimize particle generation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention replaces traditional protrusion materials with hydrogen-free amorphous carbon that can withstand high temperatures, effectively creating a durable, non-disposable solution that maintains performance throughout the ESC's service life in high-temperature semiconductor processing environments.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Force

If close contact between wafer and ESC is maintained, then electrostatic adsorption is effective, but friction generates particles

Engineering Contradiction:
Improveelectrostatic adsorption forceVSAvoidparticle generation
Core Design Contradiction:
ForceVSObject-generated harmful factors

Solution Approach 1:

The invention segments the contact surface by creating protrusions that distribute the wafer-ESC contact at discrete points rather than continuous contact. This segmentation maintains sufficient electrostatic adsorption force while minimizing the total friction area, thereby reducing particle generation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The protrusions are strategically positioned and sized to create localized contact zones that concentrate electrostatic forces where needed while leaving non-contact areas that prevent friction-induced particle generation. The local geometry is optimized to balance adsorption and particle reduction.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively prevents particle generation and attachment, ensuring high-temperature stability and conductivity, reducing the risk of protrusions falling off and improving the semiconductor manufacturing process by maintaining particle-free wafer surfaces.

Implementation Method 1

a carbon plasma is generated by using a graphite target, and a hydrogen-free amorphous carbon layer is deposited over the support surface

Methodology Applied
Scientific EffectCarbon plasma deposition: Plasma Enhanced Chemical Vapour Deposition

Implementation Method 2

the carbon plasma is filtered and/or focused using a magnetic field

Methodology Applied
Scientific EffectMagnetic field filtering and focusing: Magnetic Field

Implementation Method 3

The adhesive layer includes a plurality of adhesive parts having the same number as the number of the protrusions. Each of the adhesive parts is placed between the support surface and a corresponding one of the protrusions

Methodology Applied
Scientific EffectMetal adhesion: Adhesive

Implementation Method 4

an electrostatic chuck (ESC) uses electrostatic adsorption to fix a to-be-processed workpiece, for example, a wafer

Methodology Applied
Scientific EffectElectrostatic adsorption: Electrostatics

Data Source

PatentUS11309208B2Electrostatic chuck and method for manufacturing protrusions thereof
Publication Date: 2022.04.19 BEIJING NAURA MICROELECTRONICS EQUIP CO LTD
  • US11309208B2 patent drawing
  • US11309208B2 patent drawing
  • US11309208B2 patent drawing

AI summary

The present disclosure provides an electrostatic chuck (ESC) and a method for manufacturing the plurality of protrusions of the ESC. The electrostatic chuck includes a support surface for carrying a workpiece and the plurality of protrusions distributed at intervals on the support surface. The protrusions are formed by a hydrogen-free amorphous carbon with a resistivity ranging from 10−4 Ω·cm˜109Ω·cm. For the ESC provided by the present disclosure, the protrusions are formed by the hydrogen-free amorphous carbon and have a high hardness and a good wear resistance, which may effectively prevent a generation of particles. As such, the negative impact of the particles on the semiconductor process may be avoided, and the hydrogen does not dissociate in a high-temperature environment. Thereby, a problem that the protrusions may easily fall off and may not be suitable in the high-temperature environment (above 250° C.) may be solved.