ESD Protection Device Using Glass-Coated Metallic Particles

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Solution Overview

Problem

Conventional ESD protection devices have limitations in lowering discharge starting voltage and peak voltage, and suffer from performance degradation due to the use of resin, which lacks sufficient heat resistance and oxidation resistance, leading to characteristic degradation when static electricity is repeatedly applied.

Innovation Solution

An ESD protection device featuring a ceramic base material with opposed electrodes and a discharge auxiliary electrode film made of metallic particles coated with glass, along with an inorganic oxide and semiconductor powder, which increases the metallic particle content and enhances heat resistance, reducing discharge starting and peak voltages while preventing characteristic degradation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If resin is used to isolate metallic particles in the static electricity protective material layer, then the metallic particles are isolated from each other, but the resin degrades due to insufficient heat resistance and oxidation resistance, causing performance degradation when static electricity is applied repeatedly

Engineering Contradiction:
Improveperformance stabilityVSAvoidheat resistance
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent removes the resin component from the static electricity protective material layer, extracting the harmful element that caused degradation. The material layer consists only of metallic particles without any resin binder, eliminating the heat resistance and oxidation resistance problems associated with organic resins while maintaining particle isolation through a different mechanism.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces the degradable resin with a simple, stable structure where metallic particles are directly arranged without organic binders. This approach uses durable inorganic materials that can withstand repeated electrostatic discharge events without degradation, sacrificing the ease of particle isolation provided by resin for long-term reliability.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Ease of manufacture

If resin is used as the binding material in the static electricity protective material layer, then the metallic particles can be kneaded and formed into a layer, but the resin lacks sufficient heat resistance and oxidation resistance, leading to characteristic degradation

Engineering Contradiction:
Improvelayer formationVSAvoidcharacteristic stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent extracts the resin component from the material composition, creating a layer of metallic particles without organic binders. This eliminates the contradiction by removing the material that enabled easy formation but caused reliability problems under thermal and oxidative stress.

Inventive Principle:
Principle #2Taking out (Extraction)

3Reliability

If the ratio of metallic particles in the static electricity protective material layer is limited, then the resin can effectively isolate the particles, but the ability to lower discharge starting voltage and peak voltage is limited

Engineering Contradiction:
Improvedischarge voltage reduction capabilityVSAvoidmetallic particle ratio
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

By removing the resin component entirely, the patent enables a higher concentration of metallic particles in the protective material layer. This increases the quantity of conductive particles available for electrostatic discharge, thereby improving the ability to lower discharge starting voltage and peak voltage without being constrained by resin content limitations.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively lowers discharge starting and peak voltages and maintains stable performance over time by using glass-coated metallic particles and inorganic oxides, preventing degradation and improving reliability in ESD protection.

Implementation Method 1

metallic particles with glass covering the metallic particles

Methodology Applied
Scientific EffectGlass coating protection: Coatings

Implementation Method 2

the resin used for isolating the metallic particles from each other essentially does not have necessarily sufficient heat resistance and oxidation resistance

Methodology Applied
Scientific EffectOxidation resistance: Oxidation

Implementation Method 3

a discharge auxiliary electrode film arranged to connect the pair of opposed electrodes, wherein the discharge auxiliary electrode film contains, as its main constituents, metallic particles and glass covering the metallic particles

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS8885312B2ESD protection device and manufacturing method thereof
Publication Date: 2014.11.11 MURATA MFG CO LTD
  • US8885312B2 patent drawing
  • US8885312B2 patent drawing
  • US8885312B2 patent drawing

AI summary

An ESD protection device includes a ceramic base material, a pair of opposed electrodes provided on a surface of or in the ceramic base material, and a discharge auxiliary electrode film arranged to connect the pair of opposed electrodes, wherein the discharge auxiliary electrode film is composed of a material containing, as its main constituents, metallic particles and glass covering the metallic particles. The discharge auxiliary electrode film is formed by providing an electrode paste containing glass-coated metallic particles that have an approximately 15% rate of increase in weight at about 400° C. for about 2 hours in air, a resin binder, and a solvent so as to connect the pair of opposed electrodes to each other, and then firing at a temperature of about 600° C. or more, higher than a softening point of glass of the glass-coated metallic particles, and not +200° C. higher than the softening point.