Ester Lubricant Composition Engine Cleanliness

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Solution Overview

Problem

Current lubricating compositions for marine engines, while aiming to reduce corrosive wear and improve cleanliness, often lead to the formation of deposits due to additive decomposition, resulting in increased wear and reduced engine life.

Innovation Solution

Incorporating a lubricating composition with 2-12% by weight of esters having a viscosity of 200-1000 cSt, where the alcohol is trimethylolpropane and the acid is fatty acids with 6-24 carbon atoms, along with detergents and other additives, to enhance thermal stability and reduce varnish formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If additives are used to neutralize sulfuric acid and reduce corrosive wear, then corrosive wear is reduced, but deposits are formed that clog engine parts

Engineering Contradiction:
Improvecorrosive wear reductionVSAvoiddeposit formation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention changes the chemical composition parameters of the lubricating composition by incorporating esters with specific molecular weight ranges (viscosity at 100°C between 200-1000 cSt) and specific chemical structures (trimethylolpropane esters of fatty acids with 6-24 carbon atoms). These parameter changes enable the lubricant to maintain acid neutralization capability while reducing deposit formation through the unique thermal stability and molecular characteristics of the specified esters.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional lubricating compositions are used to reduce corrosive wear, then engine protection is improved, but engine cleanliness deteriorates due to additive decomposition

Engineering Contradiction:
Improveengine protectionVSAvoidvarnish formation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention uses a composite lubricating composition combining base oil with specific esters (trimethylolpropane esters of fatty acids with 6-24 carbon atoms and viscosity 200-1000 cSt at 100°C) in optimized proportions (2-12% by weight). This composite formulation integrates the protective properties of conventional additives with the thermal stability and cleanliness properties of the specialized esters, achieving both engine protection and cleanliness.

Inventive Principle:
Principle #40Composite materials

3Stability of the object's composition

If ester concentration is increased beyond optimal range, then thermal stability should improve, but engine cleanliness improvement is not observed

Engineering Contradiction:
Improvethermal stabilityVSAvoidvarnish formation
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The invention applies partial action by using ester concentrations within the optimized range of 2-12% by weight (preferably 3-10%, more preferably 4-10%). This partial concentration is sufficient to achieve the desired thermal stability and cleanliness improvement without the need for excessive ester content, avoiding potential negative effects of over-concentration while maintaining optimal performance.

Inventive Principle:
Principle #16Partial or excessive action

Data Source

PatentEP3684893B1Use of esters in a lubricant composition for improving the cleanliness of an engine
Publication Date: 2024.11.06 TOTALENERGIES ONETECH
  • EP3684893B1 patent drawing
  • EP3684893B1 patent drawing
  • EP3684893B1 patent drawing

AI summary

The present application relates to the use, in a lubricant composition comprising at least one base oil, of 2 to 12% by weight, relative to the weight of said lubricant composition, of an ester that has a viscosity at 100°C of between 200 and 1000 cSt, for the purpose of improving the cleanliness of an engine.