Low Viscosity Ester Lubricant for High-Temperature Engine Friction

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Solution Overview

Problem

Conventional lubricants face challenges in maintaining sufficient viscosity at high temperatures while providing low viscosity at low temperatures, leading to inefficiencies in friction reduction and wear prevention in high-temperature applications like engines, where they often require additional friction modifying additives that degrade over time.

Innovation Solution

A lubricant composition featuring low viscosity esters with a kinematic viscosity of 1 to 4 centistokes at 100°C and a KV150/KV100 ratio of 0.6 or higher, combined with a polymeric viscosity modifier, which provides effective lubrication performance at high temperatures without the need for friction modifying additives.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional lubricant base stocks are used, then the lubricant provides sufficient fluidity at low temperatures, but the viscosity at high temperatures becomes insufficient to maintain film thickness

Engineering Contradiction:
Improvehigh temperature viscosityVSAvoidfilm thickness maintenance
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent combines Group IV (PAO) and Group V (ester) base stocks in a composite formulation. The PAO provides thermal stability and consistent viscosity at high temperatures, while the ester components contribute to low-temperature fluidity and boundary lubrication. This composite approach allows the lubricant to maintain adequate film thickness across a wide temperature range without relying solely on friction modifiers.

Inventive Principle:
Principle #40Composite materials

2Temperature

If conventional lubricant base stocks are used, then the lubricant provides sufficient viscosity at high temperatures, but the viscosity at low temperatures becomes excessively high

Engineering Contradiction:
Improvehigh temperature viscosityVSAvoidlow temperature fluidity
Core Design Contradiction:
TemperatureVSEase of operation

Solution Approach 1:

The patent carefully selects and adjusts the viscosity grades and proportions of PAO and ester components to optimize the viscosity-temperature relationship. By changing the physical parameters (viscosity grades, blend ratios) of the base stocks, the formulation achieves a KV150/KV100 ratio of 0.35-0.55, ensuring adequate high-temperature viscosity while maintaining acceptable low-temperature fluidity without excessive thickening.

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If friction modifying additives are added to conventional lubricants, then friction reduction is improved, but the additives degrade in performance over time

Engineering Contradiction:
ImprovefrictionVSAvoidadditive performance stability
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent employs base stocks (PAO and esters) that inherently provide friction reduction capabilities without relying heavily on additive packages. The ester components particularly contribute to boundary lubrication through their molecular structure, creating protective films on metal surfaces. This self-service approach reduces dependence on friction modifiers that degrade over time, improving long-term performance stability.

Inventive Principle:
Principle #25Self-service

4Temperature

If polymeric viscosity modifiers are used to improve viscosity-temperature response, then high temperature viscosity is increased, but low temperature viscosity is significantly increased

Engineering Contradiction:
Improveviscosity-temperature responseVSAvoidlow temperature viscosity
Core Design Contradiction:
TemperatureVSEase of operation

Solution Approach 1:

The patent achieves improved viscosity-temperature response by changing the base stock composition (using PAO and ester blend) rather than relying on polymeric viscosity modifiers. This approach provides adequate high-temperature viscosity while avoiding the significant low-temperature thickening that would result from adding polymers, maintaining better overall ease of operation across the temperature range.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The lubricant composition achieves optimal viscosity and friction reduction across a wide temperature range, enhancing engine efficiency and reducing wear without the use of degrading additives, by maintaining sufficient film thickness and fluidity at both high and low temperatures.

Implementation Method 1

The ester exhibits a kinematic viscosity at 100° C. of 1 to 4 centistokes and a kinematic viscosity ratio at 150° C./100° C. of 0.6 or higher

Methodology Applied
Scientific EffectViscosity:

Implementation Method 2

two contacting surfaces are separated by a full lubricant fluid film and the resulting friction is referred to as hydrodynamic friction

Methodology Applied
Scientific EffectLubrication: Lubrication

Implementation Method 3

friction is determined by the friction coefficient of the chemical film formed at the two surfaces

Methodology Applied
Scientific EffectFriction: Friction

Implementation Method 4

under high load at low speed or low viscosity conditions, two contacting surfaces will be rubbing against each other and friction is determined by the friction coefficient of the chemical film formed at the two surfaces

Methodology Applied
Scientific EffectBoundary lubrication: Lubrication

Data Source

PatentUS10208269B2Low viscosity ester lubricant and method for using
Publication Date: 2019.02.19 EXXONMOBIL TECHNOLOGY & ENGINEERING CO
  • US10208269B2 patent drawing
  • US10208269B2 patent drawing
  • US10208269B2 patent drawing

AI summary

According to the present disclosure, there is provided a high-temperature lubricant composition. The composition has an amount of an ester. The ester exhibits a kinematic viscosity at 100° C. of 1 to 4 centistokes and a kinematic viscosity ratio at 150° C./100° C. of 0.6 or higher. The composition is at a temperature of 100° C. to 150° C. There is also another lubricating composition having the ester and a polymeric viscosity modifier. There are also methods for using the lubricating compositions in the crankcase of an engine.