Etch-Resist Mask Printing on Metal Surfaces With Reactive Inks

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Solution Overview

Problem

Conventional methods for applying etch-resist masks on metallic surfaces, such as copper in PCB manufacturing, suffer from issues like uncontrolled droplet spreading, reduced resolution, inconsistent line widths, and poor edge smoothness due to the use of low-viscosity inkjet materials, leading to shorts and disconnections in printed patterns.

Innovation Solution

A two-part ink composition set is used, comprising a first reactive component forming a primer layer and a second reactive component that undergoes a chemical reaction to form a bi-component material with increased viscosity, immobilizing droplets and forming an etch-resist mask through nonimpact printing, ensuring adherence to the metallic surface and resistance to etching solutions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional low-viscosity inkjet materials are used for applying etch-resist masks, then the application process is simple and fast, but the printed pattern exhibits reduced resolution, uncontrolled droplet spreading, inconsistent line widths, and poor edge smoothness

Engineering Contradiction:
Improveprint qualityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The ink composition is divided into two separate reactive components that are applied in sequence. The first component forms a primer layer, and the second component reacts with it to form the etch-resist mask. This segmentation allows each component to be optimized for its specific function, improving print quality while maintaining process simplicity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses a composite ink system consisting of two reactive components that chemically react to form the etch-resist mask. This composite approach enables better control over droplet spreading and line width consistency, as the reaction between components creates a more stable and precise printed pattern.

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional inkjet printing is used with low-viscosity materials, then the manufacturing process is fast, but the droplets spread uncontrollably causing shorts and disconnections in printed patterns

Engineering Contradiction:
Improvepattern integrityVSAvoidmanufacturing speed
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent changes the viscosity parameter of the ink material by using a two-component reactive system. The reaction between components creates a material with increased viscosity that prevents uncontrolled droplet spreading, thereby ensuring pattern integrity without significantly reducing manufacturing speed.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The first reactive component is applied as a primer layer that prepares the surface locally. The second component then reacts with this primer in a controlled manner, ensuring that each area of the printed pattern receives the appropriate chemical treatment for optimal droplet control and pattern integrity.

Inventive Principle:
Principle #3Local quality

3Manufacturing precision

If photosensitive etch-resist substance is used requiring UV exposure and chemical development, then the etch-resist mask can be formed, but the process becomes complex and time-consuming

Engineering Contradiction:
Improveetch-resist mask qualityVSAvoidprocess time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent extracts and eliminates the UV exposure and chemical development steps from the conventional photosensitive process. By using a two-component reactive ink system that self-assembles through chemical reaction, the process achieves etch-resist mask formation without requiring additional time-consuming equipment and chemical baths.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The two-component ink system performs self-service by automatically forming the etch-resist mask through the chemical reaction between components. The system self-assembles the required pattern structure without external intervention from UV exposure or chemical development processes, reducing both process complexity and time.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves high print quality with well-defined thin lines, sharp edges, and no line breaks, improving the precision and reliability of the etch-resist mask application process.

Implementation Method 1

the second reactive component undergoes a chemical reaction with the first reactive component so as to immobilize the droplets

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

image-wise printing by a nonimpact printing process on the primer layer a second liquid composition

Methodology Applied
Scientific EffectNonimpact printing:

Data Source

PatentUS20250374437A1Methods for producing an etch resist pattern on a metallic surface
Publication Date: 2025.12.04 KATEEVA INC
  • US20250374437A1 patent drawing
  • US20250374437A1 patent drawing

AI summary

Methods and composition sets for forming etch-resist masks on a metallic surface are provided. The method may include depositing a first aqueous composition comprising a first reactive component onto a metallic layer of a substrate; depositing a second aqueous composition comprising a second reactive component on selected portions of the deposited first aqueous composition to form, from a chemical reaction between the first reactive component and the second reactive component, a bi-component material mask in a pattern to protect selected regions of the metallic layer; and depositing an etch solution to remove the metallic layer in regions not protected by the bi-component material mask.