ETFE Sheet Extrusion for Strength and Transparency

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Solution Overview

Problem

Conventional ETFE sheets used for large membrane panels lack sufficient mechanical strength while maintaining transparency, and increasing thickness to enhance strength leads to defects and reduced productivity.

Innovation Solution

An ETFE sheet with a thickness of 305 to 3000 μm, produced by extrusion using a process involving a rigid and elastic roll setup, where the ETFE melt is cooled under controlled pressure and temperature conditions, ensuring low in-plane phase difference and high luminous transmittance, and meeting specific acoustic and tensile stress requirements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the thickness of the ETFE sheet is increased to enhance mechanical strength, then the tensile stress at yield improves, but the light transmittance decreases and outer appearance becomes insufficient

Engineering Contradiction:
Improvetensile stress at yieldVSAvoidlight transmittance
Core Design Contradiction:
StrengthVSIllumination intensity

Solution Approach 1:

The patent applies parameter changes by precisely controlling the cooling temperature range (50-180°C) and pressure conditions during extrusion to achieve optimal crystallinity and molecular orientation. This resolves the contradiction by enabling thick sheets (305-3000 μm) to maintain both high tensile stress and adequate light transmittance through controlled physical parameters during manufacturing

Inventive Principle:
Principle #35Parameter changes

2Strength

If the thickness of the ETFE sheet is increased to enhance mechanical strength, then the tensile stress at yield improves, but the outer appearance develops defects due to high weight

Engineering Contradiction:
Improvetensile stress at yieldVSAvoidouter appearance quality
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent changes the temperature and pressure parameters during the extrusion process to prevent defects in thick sheets. By maintaining cooling temperatures between 50-180°C and controlling the linear pressure (0.1-1000 N/cm), the process enables production of defect-free surfaces even in sheets up to 3000 μm thick, resolving the contradiction between strength enhancement and appearance quality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces an intermediary cooling mechanism using controlled temperature rolls as a mediator between the hot extruded melt and the final product. This intermediary cooling process prevents thermal shock and surface defects while allowing thick sheets to be produced with excellent appearance quality and high mechanical strength

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If compression molding method is used to produce thick ETFE sheets with fewer defects, then the outer appearance improves, but the productivity decreases

Engineering Contradiction:
Improvedefect reductionVSAvoidproduction efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent replaces the traditional compression molding mechanical system with a continuous extrusion system. By substituting the batch-process compression molding with a continuous extrusion process featuring controlled cooling rolls, the method achieves both high productivity and defect-free thick sheets, resolving the contradiction between manufacturing precision and production efficiency

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Strength

If multiple ETFE sheets are overlaid to improve mechanical strength, then the tensile stress increases, but the transparency decreases due to interfacial reflection

Engineering Contradiction:
Improvemechanical strengthVSAvoidtransparency
Core Design Contradiction:
StrengthVSIllumination intensity

Solution Approach 1:

The patent transitions from a multi-layer stacking approach (adding layers in the z-dimension) to a single-thickness extrusion approach (controlling thickness in the z-dimension directly). By extruding sheets in the range of 305-3000 μm as single layers with controlled crystallinity, the method achieves high mechanical strength without the transparency loss from multiple interfaces, resolving the contradiction between strength and transparency

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process results in an ETFE sheet with enhanced mechanical strength, transparency, and sound insulation properties, suitable for large membrane panels without compromising appearance or productivity.

Implementation Method 1

letting the sheet pass between two rolls as a pair and cooling the sheet

Methodology Applied
Scientific EffectCooling: Cooling

Implementation Method 2

the average of the surface temperatures of the two rolls is from 50 to 180°C

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 3

one of the two rolls is a rigid roll, and the other is an elastic roll

Methodology Applied
Scientific EffectElastic deformation: Elasticity

Implementation Method 4

RaId (wherein R0 is an in-plane phase difference, and d is a thickness) of at most 3.0×10^-3

Methodology Applied
Scientific EffectBirefringence: Birefringence

Data Source

PatentEP3187525B1Ethylene-tetrafluoroethylene copolymer sheet and method for producing same
Publication Date: 2024.07.03 AGC INC
  • EP3187525B1 patent drawingFigure 1~2
  • EP3187525B1 patent drawingFigure 3~5
  • EP3187525B1 patent drawingFigure 6~7

AI summary

To provide an ethylene/tetrafluoroethylene copolymer sheet excellent in the mechanical strength and the outer appearance, continuously produced by extrusion, and a process for producing it. An ethylene/tetrafluoroethylene copolymer sheet obtained by extrusion, which is characterized by having Ro/d (wherein Ro is an in-plane phase difference [unit: nm], and d is a thickness [unit: nm]) of at most 3.0×10-3, and a thickness of more than 300 µm, and a process for producing it.