Ethane Inventory Production for Faster LNG Train Start-Up

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Solution Overview

Problem

Current methods for starting up an LNG production plant are inefficient, requiring several weeks to produce a sufficient ethane inventory due to low ethane extraction efficiency and causing significant gas flaring, with challenges in handling lean natural gas feed streams and safety issues with ethylene substitution.

Innovation Solution

A process involving a propane pre-cooled mixed refrigerant liquefaction facility with a main heat exchanger and mixed refrigerant circuit, where a bypass stream of dry sweet scrubbed gas is circulated to progressively cool and condense, separating fractions rich in nitrogen and methane, and ethane, with the ethane-saturated stream being cooled and stored, achieving high ethane recovery efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If a scrub column is used to extract ethane from natural gas feed stream at reduced flow rate, then ethane can be recovered for mixed refrigerant inventory, but the extraction efficiency is only around 5% and several weeks of operation are required

Engineering Contradiction:
Improveethane recovery quantityVSAvoidstart-up time
Core Design Contradiction:
Quantity of substanceVSLoss of time

Solution Approach 1:

The patent changes the operating parameters by running the natural gas feed stream at normal operating flow rate (30-40% of full rate) instead of reduced flow rate, and by using the propane circuit to provide cooling to the scrub column at optimized temperatures. This combination of parameter changes achieves both high ethane extraction efficiency (>95%) and reasonable start-up time (several days rather than weeks).

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces the propane circuit as an intermediary cooling system to enhance the scrub column's ethane extraction capability. The propane circuit provides the necessary cooling duty to the scrub column, enabling efficient ethane condensation and separation from the natural gas feed stream without requiring the feed stream to be run at very low flow rates.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Quantity of substance

If natural gas feed stream is run through scrub column at reduced flow rate (30-40% of normal), then ethane extraction is possible, but significant quantities of gas must be flared and liquid management issues occur

Engineering Contradiction:
Improveethane extractionVSAvoidgas flaring and liquid management issues
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent changes the flow rate parameter from reduced (30-40% of normal) to normal operating flow rate. This eliminates the need to flare significant quantities of gas and avoids liquid management issues in the pipelines, while still achieving high ethane extraction efficiency through the enhanced cooling provided by the propane circuit.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts what would normally be waste streams (the natural gas feed stream that would be flared and the liquids causing management issues) into beneficial products. By running the feed stream at normal flow rate through the enhanced scrub column, ethane is efficiently extracted (>95%) while the remaining gas can be used as fuel gas or further processed, eliminating flaring and liquid management problems.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Quantity of substance

If propane compression circuit operates at low load during ethane production, then ethane extraction can proceed, but recycle valves must be used and compression efficiency is reduced

Engineering Contradiction:
Improveethane productionVSAvoidpropane compression efficiency
Core Design Contradiction:
Quantity of substanceVSUse of energy by moving object

Solution Approach 1:

The patent changes the operating parameters of the propane compression circuit by optimizing the cooling duty provided to the scrub column. This allows the propane compressors to operate at higher load levels (avoiding the need for recycle valves) while still achieving the necessary ethane extraction efficiency. The parameter changes in temperature and pressure profiles optimize both ethane production and compression efficiency simultaneously.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process significantly reduces the time to produce ethane inventory from weeks to days, achieving over 95% ethane extraction efficiency and minimizing flaring, while allowing for quicker LNG production startup.

Implementation Method 1

a bypass stream of dry sweet scrubbed gas is circulated to progressively cool and condense, separating fractions rich in nitrogen and methane, and ethane

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 2

separating fractions rich in nitrogen and methane, and ethane, with the ethane-saturated stream being cooled and stored

Methodology Applied
Scientific EffectFractionation: Fractionation

Implementation Method 3

cooling the pressurized bypass gas stream using the propane refrigeration circuit to produce a cooled pressurized bypass gas stream

Methodology Applied
Scientific EffectRefrigeration cooling: Cooling

Implementation Method 4

the cooled pressurized bypass gas is cooled as it expands across an expansion valve into the shell side circuit of the main heat exchanger

Methodology Applied
Scientific EffectJoule-Thomson effect: Joule-Thomson Effect

Implementation Method 5

evaporating the cooled liquid bypass stream in the shell side circuit of the main heat exchanger to produce a first fraction rich in nitrogen and methane and a second fraction rich in ethane

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 6

cooling the ethane-saturated pressurized bypass stream in the propane refrigerant circuit to produce a condensed heavy mixed refrigerant stream containing liquid ethane for storage

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentUS10060674B2Production of ethane for start-up of an LNG train
Publication Date: 2018.08.28 WOODSIDE ENERGY TECH PTY LTD
  • US10060674B2 patent drawing
  • US10060674B2 patent drawing
  • US10060674B2 patent drawing

AI summary

A process is described herein for the production of a selected quantity of ethane as a component of a production inventory of mixed refrigerant for an LNG production plant prior to start-up of the LNG production plant.