Ether Base Stock Lubricant for Engine Oxidative Stability

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Solution Overview

Problem

Lubricant compositions for internal combustion engines face challenges in achieving low volatility with a desirable viscosity profile while maintaining good oxidative stability, often requiring high antioxidant levels that are costly and can have environmental and compatibility issues.

Innovation Solution

A lubricant composition featuring an ether base stock with specific alkyl and cycloalkyl groups, combined with aminic and phenolic antioxidants, which reduces the need for high antioxidant concentrations while enhancing oxidative stability and fuel economy performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional base stocks are used to achieve good oxidative stability, then high antioxidant levels are required, but this increases cost and causes environmental and compatibility issues

Engineering Contradiction:
Improveoxidative stabilityVSAvoidenvironmental impact and compatibility issues
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical structure parameter of the base stock from conventional hydrocarbons to ether compounds with specific molecular structures (formula I). This structural parameter change inherently provides oxidation resistance, reducing the need for high levels of antioxidant additives and their associated environmental and compatibility problems.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite lubricant system combining ether base stocks with specific antioxidant packages. The ether base stock serves as both the lubricating medium and an inherent oxidation-resistant component, while complementary additives provide synergistic protection, reducing the overall burden on any single additive system.

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If viscosity is reduced to improve fuel economy, then low-temperature flow improves, but oxidative stability may be compromised

Engineering Contradiction:
Improvefuel economyVSAvoidoxidative stability
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent changes the molecular structure parameter to ether compounds that maintain appropriate viscosity at operating temperatures while ensuring low-temperature fluidity. The ether functional group and specific carbon chain structures provide a balanced viscosity profile that supports both fuel economy and oxidation resistance without requiring extreme viscosity modifications.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP4095220B1Ether-based lubricant compositions, methods and uses
Publication Date: 2024.07.31 CASTROL LTD
  • EP4095220B1 patent drawingFigure 1
  • EP4095220B1 patent drawing
  • EP4095220B1 patent drawing

AI summary

The present invention provides a lubricant composition comprising a base oil of lubricating viscosity, wherein the base oil comprises an ether base stock of formula (A), where: Ra and Rb are aliphatic hydrocarbyl groups and may be the same or different; the lubricant composition further comprising at least one aminic anti-oxidant and at least one phenolic anti-oxidant. In some embodiments, the ether base stock has the formula (1), where: R1 R2, R3, R4, R5 and R6 are as defined herein. The lubricant composition may be used for lubricating a surface in an internal combustion engine as well as for improving the fuel economy performance and/or piston cleanliness performance of an engine and/or a vehicle, such as an automotive vehicle associated with an internal combustion engine.