Ethoxylated Alcohol Formulation for Emulsion Resolution in Acidic Brine

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Solution Overview

Problem

Current emulsion-modifier formulations for oil production are often toxic, environmentally unfriendly, and complex, failing to effectively prevent or resolve emulsions in high brine and acidic environments, which complicates oil recovery and poses formation damage risks.

Innovation Solution

A formulation comprising ethoxylated alcohols and solvents, specifically designed to function as non-emulsifiers, weak emulsifiers, or demulsifiers, effectively preventing or resolving water and oil emulsions in high brine or acidic environments without the need for additional surfactants or environmentally harmful solvents, utilizing a combination of ethoxylated alcohols and ethers that can be used in both micro-emulsion and 100% active formats.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional emulsion-modifier formulations are used, then emulsion prevention or resolution is achieved, but toxicity and environmental harm increase

Engineering Contradiction:
Improveemulsion prevention effectivenessVSAvoidtoxicity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and eliminates harmful components (formaldehyde, phenol-formaldehyde resins, amines, quaternary salts, polyamines, polyimines, and BTEX solvents) from conventional emulsion-modifier formulations, replacing them with non-toxic alternatives that maintain effectiveness while removing toxicity

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical composition parameters of the formulation by specifying precise weight percentage ranges for each component (water: 70-95%, alcohol: 2-30%, ethoxylated alcohol: 2-30%, ester: 1-20%, ether: 1-20%) to achieve optimal performance with non-toxic ingredients

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If complex formulations are used to provide application possibilities over a wide range of circumstances, then versatility is improved, but formulation complexity and cost increase

Engineering Contradiction:
Improveapplication rangeVSAvoidformulation complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent creates a universal formulation that can function as non-emulsifier, weak emulsifier, or demulsifier depending on the specific crude oil and downhole conditions, eliminating the need for multiple specialized products while maintaining broad applicability across different oil grades and environments

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges multiple functional components (water, alcohol, ethoxylated alcohol, ester, and ether) into a single integrated formulation that provides both prevention and resolution capabilities, simplifying the overall system while expanding application possibilities

Inventive Principle:
Principle #5Merging (Combining)

3Object-affected harmful factors

If environmental friendliness is improved by removing harmful solvents, then environmental harm is reduced, but formulation effectiveness in harsh environments may worsen

Engineering Contradiction:
Improveenvironmental harmVSAvoideffectiveness in harsh environments
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent introduces specific intermediaries (ethoxylated alcohols with 3-20 ethylene oxide units and specific ether/ester components) that mediate between the environmental friendliness requirement and the harsh environment effectiveness requirement, enabling the formulation to function in high brine and acidic conditions without harmful solvents

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes concentration parameters of each component (particularly ethoxylated alcohol at 2-30% and alcohol at 2-30%) to ensure sufficient effectiveness in harsh environments while maintaining environmental friendliness through the absence of toxic substances

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The formulation effectively prevents or resolves emulsions in high brine and acidic environments, avoiding formation damage and being applicable to a wide range of crude oils, with the advantage of being environmentally friendly and cost-effective, while avoiding the need for polymer-based compositions.

Implementation Method 1

The present invention relates to formulations containing non-ionic surfactants or mixtures thereof and the use of such formulations for the prevention, breakage/resolving or modification of emulsions

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentUS20240117240A1Formulations Containing Non-Ionic Surfactants as Emulsion-Modifiers in Oil Treatments
Publication Date: 2024.04.11 SASOL CHEMICALS GMBH
  • US20240117240A1 patent drawing
  • US20240117240A1 patent drawing

AI summary

A formulation according to the invention that can be utilized in the prevention and/or resolving of water and oil emulsions, is described. These formulations have been found to modify water and oil emulsions, and to be very effective non-emulsifiers/weak emulsifiers and/or demulsifiers, specifically in high brine or highly acidic environments, for water and crude oil emulsions. The formulation comprises at least one ethoxylated alcohol with a molecular structure as shown in formula 1: R—O—(C2H4O)n—H (1) wherein R comprises linear or branched alkyl groups having from 6 to 18 carbon atoms and n is from 3 to 20.