Ethylene Alpha-Olefin Interpolymer Flowability

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Solution Overview

Problem

Low molecular weight ethylene/alpha-olefin interpolymers exhibit stickiness during pellet flow, which is a challenge for their use in adhesive formulations due to blocking characteristics.

Innovation Solution

An ethylene/C3-C6 alpha-olefin interpolymer composition with specific properties, including a High Comonomer Content (HCC) value and aged flowability, is developed to reduce stickiness and improve flowability, meeting the equation HCC(wt %)≥−648.6[(wt %)(cc)/(g)]×(density)+569.4(wt %) and aged flowability ≥130 g/sec.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If low molecular weight ethylene/alpha-olefin interpolymers are used, then adhesive formulation capability is improved, but pellet flowability deteriorates due to stickiness and blocking

Engineering Contradiction:
Improveadhesive formulation capabilityVSAvoidpellet flowability
Core Design Contradiction:
Adaptability or versatilityVSEase of operation

Solution Approach 1:

The patent applies parameter changes by precisely controlling the molecular weight distribution (Mw/Mn ratio between 1.5-3.0) and comonomer content (1-20 wt% C3-C6 alpha-olefin) of the ethylene/alpha-olefin interpolymer. By adjusting these physical and chemical parameters within specific ranges, the patent achieves both good flowability (aged flowability ≥130 g/sec) and adhesive performance, resolving the contradiction between formulation capability and pellet flowability.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If ethylene/alpha-olefin interpolymer is used, then processing efficiency is improved, but pellet stickiness increases causing blocking during flow

Engineering Contradiction:
Improveprocessing efficiencyVSAvoidpellet stickiness
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent converts the potentially harmful stickiness characteristic into a beneficial feature by carefully controlling the comonomer type and content. The C3-C6 alpha-olefin comonomer, when present in optimized amounts (1-20 wt%), provides sufficient adhesion for processing efficiency while the specific molecular weight distribution (Mw/Mn: 1.5-3.0) prevents excessive stickiness that would cause blocking. The aged flowability test (≥130 g/sec) confirms that the material maintains flowability even after aging, transforming what could be a harmful sticky characteristic into a controlled, beneficial property.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Ease of operation

If molecular weight is reduced for better flowability, then pellet flow improves, but adhesive strength deteriorates

Engineering Contradiction:
Improvepellet flowabilityVSAvoidadhesive strength
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent employs composite material principles by creating an ethylene/alpha-olefin interpolymer with a specific composite structure: a polyethylene backbone with grafted alpha-olefin side chains. This composite molecular architecture allows the material to exhibit both low molecular weight characteristics (for flowability, with Mw ≤40,000) and sufficient adhesive strength through the polar alpha-olefin groups. The controlled molecular weight distribution (Mw/Mn: 1.5-3.0) ensures that the composite structure maintains integrity while providing good flowability (aged flowability ≥130 g/sec).

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS11667819B2Ethylene/C3-C6 alpha-olefin interpolymers with improved pellet flowability
Publication Date: 2023.06.06 DOW GLOBAL TECHNOLOGIES LLC
  • US11667819B2 patent drawing
  • US11667819B2 patent drawing
  • US11667819B2 patent drawing

AI summary

A composition is provided, which comprises an ethylene/C3-C6 alpha-olefin interpolymer, and wherein the interpolymer comprises the following properties:a) an HCC value that meets the following equation:HCC(wt %)≥−648.6[(wt %)(cc)/(g)]×(density)+569.4(wt %);b) an aged flowability ≥130 g/sec.