Ethylene Copolymer Blend Encapsulant for Solar Module Adhesion

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Solution Overview

Problem

Current solar cell modules face challenges with encapsulant materials that lack superior adhesion to adjacent layers, leading to potential moisture ingress and de-lamination, especially in thin film solar cell modules where edge sealing is costly and process-intensive.

Innovation Solution

A solar cell module utilizing a blend composition of ethylene copolymers with specific melt flow rates and comonomer ratios, which forms a sheet that serves as an encapsulant layer, providing enhanced adhesion and water resistance to glass and other materials, thereby improving the weatherability and sealing of the module.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional encapsulant materials are used, then manufacturing cost is reduced, but adhesion to adjacent layers deteriorates leading to moisture ingress and de-lamination

Engineering Contradiction:
Improveadhesion to adjacent layersVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent uses a composite material system consisting of a polyolefin copolymer base resin combined with a polyacid-containing copolymer additive. This composite approach provides superior adhesion to glass and other adjacent layers while maintaining compatibility with conventional manufacturing processes, resolving the contradiction between reliability and ease of manufacture

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition parameters of the encapsulant by incorporating polyacid-containing copolymers at specific concentrations (0.1-10 wt%). This parameter change enhances adhesion properties without significantly altering the processing characteristics, allowing improved reliability while maintaining ease of manufacture

Inventive Principle:
Principle #35Parameter changes

2Reliability

If edge sealing is implemented in thin film solar cell modules, then moisture ingress is prevented, but manufacturing complexity and cost increase

Engineering Contradiction:
Improvemoisture resistanceVSAvoidedge sealing process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent extracts the moisture barrier function from the edge sealing process and integrates it into the bulk encapsulant material itself. By incorporating polyacid-containing copolymers that provide superior adhesion and moisture resistance throughout the encapsulant layer, the need for complex edge sealing processes is eliminated, reducing device complexity while maintaining reliability

Inventive Principle:
Principle #2Taking out (Extraction)

3Illumination intensity

If encapsulant material with high transparency is used, then sunlight transmission to solar cells is improved, but adhesion strength to adjacent layers deteriorates

Engineering Contradiction:
Improvesunlight transmissionVSAvoidadhesion strength
Core Design Contradiction:
Illumination intensityVSStrength

Solution Approach 1:

The patent applies local quality by concentrating the adhesion-enhancing polyacid-containing copolymer at the interfaces with adjacent layers (glass, solar cells, backsheet), while the bulk encapsulant maintains high transparency through the use of clear polyolefin copolymers. This localized approach ensures both sunlight transmission and adhesion strength are optimized

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ethylene copolymer blend composition ensures strong adhesion to glass and other materials, reducing moisture ingress and enhancing the long-term weatherability and durability of solar cell modules, particularly in thin film configurations.

Implementation Method 1

The ethylene copolymer blend composition ensures strong adhesion to glass and other materials

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

providing enhanced adhesion and water resistance to glass and other materials, thereby improving the weatherability and sealing of the module

Methodology Applied
Scientific EffectWater resistance: Hydrophobe

Data Source

PatentUS8080727B2Solar cell modules comprising an encapsulant sheet of a blend of ethylene copolymers
Publication Date: 2011.12.20 DOW GLOBAL TECHNOLOGIES LLC
  • US8080727B2 patent drawing
  • US8080727B2 patent drawing

AI summary

Disclosed is a solar cell module comprising a polymeric encapsulant sheet, wherein the polymeric encapsulant sheet comprises a blend composition of an ethylene copolymer A and an ethylene copolymer B, the blend composition having a melt flow rate of less than 100 g/10 min, as determined in accordance with ASTM D1238 at 190° C. and 2.16 kg, and wherein the ethylene copolymer A comprises copolymerized units of ethylene and about 3 to about 20 wt % of an ester or anhydride of a C4-C8 unsaturated acid having two carboxylic acid groups and the ethylene copolymer B comprises copolymerized units of ethylene and about 6 to about 40 wt % of a polar monomer selected from the group consisting of vinyl acetate, alkyl (meth)acrylates, and mixtures thereof.