Ethylene Copolymer Viscosity Modifiers Preventing Flocculation

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Solution Overview

Problem

Current rheology modifiers for lubrication oils, particularly those derived from ethylene-alpha-olefin copolymers, tend to flocculate or aggregate at higher ethylene contents, leading to high viscosity issues and potential clogging in engines, necessitating the development of new compositions that maintain low temperature solution rheology properties and shear stability.

Innovation Solution

The use of compositionally disperse or crystallinity disperse polymeric compositions formed from two distinct ethylene-based copolymers with specific ethylene content, molecular weight, and heat of fusion ranges, which are synthesized using metallocene-based catalysts to control monomer distribution and chain architecture, preventing flocculation and maintaining viscosity stability across temperature ranges.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If higher ethylene content VI improvers are used to improve oil thickening and shear stability, then thickening efficiency and shear stability are improved, but the lubrication fluid tends to flocculate or aggregate leading to high viscosity regions and precipitates that can clog pumps and passageways

Engineering Contradiction:
Improveshear stabilityVSAvoidflocculation and precipitation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies parameter changes by precisely controlling the ethylene content within 60-85 wt% range and molecular weight within 50,000-150,000 g/mol, along with specifying melt flow rate and density parameters. This optimization resolves the contradiction by finding the optimal parameter range where sufficient thickening efficiency and shear stability are achieved while preventing flocculation and precipitation that occur at higher ethylene contents.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by blending ethylene-alpha-olefin copolymer with ethylene-olefin-diene terpolymer in specific ratios (5-50% and 50-95% respectively). This composite approach allows the formulation to achieve high shear stability and thickening efficiency from the copolymer component while the terpolymer component prevents aggregation and flocculation, thus resolving the contradiction between improved reliability and prevention of harmful precipitation.

Inventive Principle:
Principle #40Composite materials

2Temperature

If higher ethylene content copolymers are used to increase viscosity, then viscosity index improvement is enhanced, but low temperature solution rheology properties deteriorate due to flocculation and gel formation

Engineering Contradiction:
Improveviscosity indexVSAvoidlow temperature solution rheology
Core Design Contradiction:
TemperatureVSEase of operation

Solution Approach 1:

The patent optimizes multiple parameters simultaneously: ethylene content (60-85 wt%), molecular weight (50,000-150,000 g/mol), and melt flow rate (0.5-5 g/10 min). This multi-parameter optimization ensures that the polymer provides sufficient viscosity index improvement while maintaining good low temperature solution rheology by preventing flocculation that would otherwise occur at higher ethylene contents.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The blended composite of ethylene-alpha-olefin copolymer and ethylene-olefin-diene terpolymer resolves the temperature-related contradiction. The copolymer provides viscosity index improvement across the temperature range, while the terpolymer component ensures good low temperature solution rheology by preventing aggregation and gel formation, thus maintaining ease of operation at low temperatures.

Inventive Principle:
Principle #40Composite materials

3Temperature

If ethylene-based copolymers with high ethylene content are used as rheology modifiers, then lubrication properties at high temperature are improved, but clogging of pumps and passageways occurs due to precipitate formation

Engineering Contradiction:
Improvehigh temperature lubricationVSAvoidclogging prevention
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent specifies precise parameter ranges: ethylene content of 60-85 wt% and molecular weight of 50,000-150,000 g/mol. These controlled parameters ensure that the polymer maintains adequate high temperature lubrication properties through sufficient viscosity, while preventing the excessive thickening and precipitate formation that would cause clogging of pumps and passageways.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite formulation blends ethylene-alpha-olefin copolymer (5-50%) with ethylene-olefin-diene terpolymer (50-95%). The copolymer provides the necessary high temperature lubrication through viscosity enhancement, while the terpolymer component acts as a dispersant that prevents aggregation and precipitate formation, thereby preventing clogging and maintaining reliability in the lubrication system.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These polymeric compositions exhibit enhanced thickening efficiency, shear stability, and low temperature viscosity performance, reducing the risk of engine clogging and improving lubrication efficiency without adverse effects on viscosity.

Implementation Method 1

synthesized using metallocene-based catalysts to control monomer distribution and chain architecture

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

Components of VI improvers derived from ethylene-alpha-olefin copolymers modify the rheological behavior to increase the lubricant viscosity and promote a more constant viscosity over a wider range of temperatures

Methodology Applied
Scientific EffectViscoelasticity: Viscoelasticity

Implementation Method 3

crystallinity disperse polymeric compositions formed from two distinct ethylene-based copolymers with specific ethylene content, molecular weight, and heat of fusion ranges

Methodology Applied
Scientific EffectCrystallisation: Crystallisation

Data Source

PatentEP2598572B1Ethylene based copolymer compositions as viscosity modifiers and methods for making them
Publication Date: 2020.03.18 EXXONMOBIL CHEMICAL PATENTS INC
  • EP2598572B1 patent drawing
  • EP2598572B1 patent drawing
  • EP2598572B1 patent drawing

AI summary

Polymeric compositions and methods for making and using the same are provided. The polymeric composition can include a first ethylene-based copolymer and a second ethylene -based copolymer. The first ethylene-based copolymer can have a weight percent of ethylene-derived units based on a weight of the polymeric composition (EA) ranging from about 35 wt% to about 52 wt% and a weight-average molecular weight (MWA) of less than or equal to 130,000. The second ethylene-based copolymer can have a weight percent of ethylene-derived units based on the weight of the polymeric composition (EB) ranging from about 65 wt% to about 85 wt% and a weight-average molecular weight (MWB) of less than 130,000.