Eutectic Flavor Systems Stabilizing Ingredients in Low Water Environments

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Solution Overview

Problem

Current water-based liquid food systems have insufficient solubility properties for certain ingredients, leading to stability issues, particularly in low pH environments, where flavors like citrus can be unstable and prone to oxidation and acid-catalyzed degradation.

Innovation Solution

A liquid system comprising a first and second component, selected from carbohydrates, sugar alcohols, food-grade acids, and non-aqueous solvents like glycerin, with a melting point lower than each component and containing 7% or less water, is used to stabilize ingredients against oxidation and acid degradation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If water-based liquid food systems are used, then the system is simple and inexpensive, but solubility properties are insufficient and ingredient stability is poor

Engineering Contradiction:
Improveingredient stabilityVSAvoidsystem complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses composite liquid systems combining multiple components (sugars, polyols, acids, non-aqueous solvents) to create a eutectic mixture that provides both improved ingredient stability and solubility. The composite nature of the system allows synergistic effects that neither component achieves alone, resolving the contradiction between stability and complexity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes key parameters of the liquid system including water content (reducing to 7% or less), pH level (maintaining low pH), and composition ratios to achieve optimal stability. By systematically adjusting these parameters, the system achieves high ingredient stability while maintaining reasonable complexity through defined compositional ranges.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If water content is reduced to improve solubility and stability, then ingredient stability improves, but the system becomes more complex to formulate

Engineering Contradiction:
Improveingredient stabilityVSAvoidformulation ease
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent defines specific parameter ranges including water content (≤7%), pH levels, and component ratios that simplify the formulation process. By establishing these defined parameters, the patent makes low-water formulation systematic and reproducible, reducing the complexity burden despite the reduced water content requirement.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The use of composite eutectic systems with multiple components in specific ratios creates a formulation framework that guides manufacturing. The defined composite structure provides clear formulation directions, making the reduced-water system easier to manufacture through established compositional guidelines.

Inventive Principle:
Principle #40Composite materials

3Adaptability or versatility

If citrus flavors are added to low pH aqueous systems, then flavor variety is enhanced, but the flavors become unstable and prone to degradation

Engineering Contradiction:
Improveflavor varietyVSAvoidflavor stability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent modifies the liquid system parameters (reducing water content to ≤7%, adjusting pH, changing composition) to create an environment where citrus flavors remain stable. These parameter changes prevent the degradation that occurs in traditional aqueous low-pH systems, allowing flavor variety without sacrificing stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the typically harmful effect of low pH (which causes citrus flavor degradation) into a beneficial stable environment by removing water and creating a eutectic system. The low pH that would normally harm citrus flavors becomes part of a stable composite system that preserves them, turning a harmful factor into a beneficial one.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Adaptability or versatility

If more ingredients are added to water-based systems, then product functionality is enhanced, but solubility limitations are exceeded and stability is compromised

Engineering Contradiction:
Improveproduct functionalityVSAvoidsystem stability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The composite eutectic liquid system provides an enhanced solubility environment that can accommodate multiple ingredients (sweeteners, flavors, functional components) without exceeding solubility limits. The synergistic composite structure allows greater ingredient diversity while maintaining system stability, resolving the contradiction between functionality and stability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system provides enhanced stability and solubility for active ingredients, maintaining their integrity for at least 13 weeks at 40°C and up to a year at room temperature, reducing water activity and preventing crystallization, while maintaining flavor profiles and reducing off-note intensities.

Implementation Method 1

the system comprises 7% or less water

Methodology Applied
Scientific EffectWater activity reduction:

Implementation Method 2

the system has a melting point lower than each of the components

Methodology Applied
Scientific EffectEutectic effect:

Data Source

PatentUS11219228B2Eutectic flavor systems
Publication Date: 2022.01.11 FIRMENICH SA
  • US11219228B2 patent drawing
  • US11219228B2 patent drawing
  • US11219228B2 patent drawing

AI summary

Provided is a liquid system comprising a first component and a second component the components selected from the group consisting of carbohydrates, sugar alcohols, food grade acids, food grade non-aqueous solvents and food grade salts wherein: a. the second component is different than the first component; b. the system has a melting point lower than each of the components; and c. the liquid system comprises 7% or less water. The systems are useful for protecting an active ingredient in a food system wherein the ingredient is stable at room temperature and retains its sensory properties after being diluted into an aqueous beverage for example to form a flavored aqueous beverage.