EUV Lithography Mask Barrier Layer Design

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Solution Overview

Problem

The semiconductor industry faces challenges in manufacturing high-resolution lithography masks, particularly in extreme ultraviolet (EUV) lithography, due to issues such as image distortion, inter-diffusion of layers, and degradation of EUV light intensity, which affect the complexity and efficiency of processing and manufacturing.

Innovation Solution

A lithography mask is fabricated using a substrate with a reflective multilayer, a barrier layer, and an absorber layer, where the barrier layer prevents inter-diffusion and is selectively etched to form the final pattern, and the absorber layer absorbs radiation, with a thickness of the barrier layer being less than or equal to 10 nm to minimize EUV light absorption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If a barrier layer is added to prevent inter-diffusion, then layer stability is improved, but device complexity increases

Engineering Contradiction:
Improvelayer stabilityVSAvoiddevice complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

A barrier layer is introduced as an intermediary component between the reflective multilayer and the absorber layer. This barrier layer prevents inter-diffusion between the adjacent layers, maintaining layer stability and composition integrity during EUV lithography processing.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The lithography mask employs a composite structure consisting of multiple functional layers including a reflective multilayer, a barrier layer, and an absorber layer. Each layer is composed of specific materials selected for their optical and structural properties, creating a composite system that achieves the desired performance.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the barrier layer thickness is increased to improve coverage, then protection is improved, but EUV light absorption increases

Engineering Contradiction:
ImproveprotectionVSAvoidEUV light absorption
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The thickness of the barrier layer is precisely controlled and optimized to be between 0.1 nm and 10 nm. This parameter optimization ensures that the barrier layer is sufficiently thick to prevent inter-diffusion and provide adequate protection, while remaining thin enough to minimize absorption of EUV light and maintain high reflectivity.

Inventive Principle:
Principle #35Parameter changes

3Measurement precision

If EUV light intensity is increased to improve resolution, then measurement precision is improved, but image distortion increases

Engineering Contradiction:
ImproveresolutionVSAvoidimage distortion
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The barrier layer is deposited beforehand on the reflective multilayer to prevent inter-diffusion that could cause image distortion. Additionally, the optimized thin barrier layer design cushions against excessive EUV light absorption, allowing high-intensity EUV light to be used for improved resolution while minimizing the harmful effect of image distortion.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration minimizes image distortion, enhances EUV light reflectivity, and improves the manufacturing efficiency by preventing inter-diffusion and maintaining high reflectivity, thereby supporting the production of smaller and more complex semiconductor circuits.

Implementation Method 1

a substrate, a reflective multiplayer (ML) on the substrate

Methodology Applied
Scientific EffectReflection: Reflection

Implementation Method 2

an absorber layer over the barrier layer

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Data Source

PatentUS9995999B2Lithography mask
Publication Date: 2018.06.12 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US9995999B2 patent drawing
  • US9995999B2 patent drawing
  • US9995999B2 patent drawing

AI summary

A lithography mask includes a substrate, a reflective multilayer (ML) on the substrate, and a barrier layer on the reflective ML. The barrier layer includes at least one material selected from the group consisting of ruthenium nitride, hafnium oxide, aluminum nitride, boron carbide, boron nitride, and a combination thereof.