EUV Lithography Mask Blank with Particle Trapping Coating

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Solution Overview

Problem

In EUV photolithography, contaminant particles reduce the yield of microelectronic devices by shielding mask patterns, and existing cleaning methods like vacuum and isopropyl alcohol/ethanol wipe-downs are not effective for maintaining cleanliness in critical components and routes through which masks pass, especially in delicate or small components.

Innovation Solution

A photomask with a modified surface or nano-fiber network coating that traps particulate matter, utilizing materials like carbon nanotubes, titanium oxide, or zinc oxide nanowires to enhance electron affinity and van der Waals interactions, forming a mesh structure to physically trap particles, and potentially modifying the surface to be more hydrophobic or hydrophilic for improved cleaning efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If vacuum and isopropyl alcohol/ethanol wipe-downs are used for cleaning, then some cleaning effect is achieved, but they are not effective for maintaining cleanliness in critical components and routes through which masks pass

Engineering Contradiction:
Improvecleanliness maintenanceVSAvoidcleaning effectiveness
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent applies porous materials (nano-fiber networks with pore sizes of 1-100 nm) coated on mask surfaces to trap particulate contaminants. The porous structure allows particles to be captured within the network while maintaining optical transparency, effectively preventing contamination in critical mask areas where traditional cleaning methods fail.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent introduces a particle trapping layer as an intermediary between the mask surface and contaminants. This layer acts as a mediator that captures particles through physical trapping and electrostatic interactions, protecting the underlying mask structures without requiring direct contact cleaning that might damage delicate components.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If traditional cleaning methods are used, then the process is simple, but they cannot maintain ultra-clean surfaces critical for finer feature production

Engineering Contradiction:
Improvesurface cleanlinessVSAvoidcleaning system complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies particle trapping layers to masks before they are exposed to contaminants. This preliminary protective action prevents contamination accumulation during storage and handling, eliminating the need for complex cleaning systems while maintaining ultra-clean surfaces required for finer feature production.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent applies particle trapping layers selectively to critical areas of masks where contamination would most impact manufacturing precision. This localized application maintains surface cleanliness in critical regions without requiring complex system-wide cleaning solutions.

Inventive Principle:
Principle #3Local quality

3Reliability

If masks are cleaned frequently to maintain cleanliness, then contamination is reduced, but productivity is lost due to cleaning time and potential damage to delicate components

Engineering Contradiction:
Improvecontamination controlVSAvoidmask availability
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent enables masks to self-trap and retain particles on their surfaces through the particle trapping layer. This self-service mechanism continuously maintains contamination control without requiring external cleaning interventions, keeping masks available for production and eliminating productivity loss associated with frequent cleaning cycles.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces particulate contamination on mask surfaces and in lithography tool routes, enhancing the cleanliness and yield of microelectronic devices by physically trapping particles, thus maintaining ultra-clean surfaces critical for finer feature production.

Implementation Method 1

utilizing materials like carbon nanotubes, titanium oxide, or zinc oxide nanowires to enhance electron affinity and van der Waals interactions, forming a mesh structure to physically trap particles

Methodology Applied
Scientific Effectvan der Waals interactions: Van der Waals Force

Implementation Method 2

utilizing materials like carbon nanotubes, titanium oxide, or zinc oxide nanowires to enhance electron affinity and van der Waals interactions

Methodology Applied
Scientific EffectElectron affinity: Electron Paramagnetic Resonance

Data Source

PatentUS11287754B2Mask blank for lithography and method of manufacturing the same
Publication Date: 2022.03.29 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US11287754B2 patent drawing
  • US11287754B2 patent drawing
  • US11287754B2 patent drawing

AI summary

A mask for cleaning a lithography apparatus includes a mask substrate and a coating provided on a surface of the mask substrate. The coating is configured to trap particulate contaminant matter from the lithography apparatus. A method of cleaning a lithography tool is also provided preparing a cleaning mask including a particle trapping layer formed on a substrate. The method includes transferring the cleaning mask through a mask transferring route of the lithography tool. Subsequently, the method includes analyzing a particle trapped by the particle trapping layer.