EUV Micropatterning via Photosensitivity Assisting Layer

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Solution Overview

Problem

Photolithography techniques using extreme ultraviolet rays face challenges in forming clear micropatterns without pattern collapse as patterns are miniaturized, leading to the need for a method that prevents pattern collapse while maintaining effective patterning.

Innovation Solution

A method involving the formation of an etching target film on a substrate, followed by a photosensitivity assisting layer terminated with a hydrophilic group, an adhesive layer forming a covalent bond with the hydrophilic group, and a photoresist film, which allows for patterning without pattern collapse by utilizing secondary electrons excited by EUV light.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If photolithography techniques using extreme ultraviolet rays are used to form micropatterns, then patterning capability is improved, but pattern collapse occurs as patterns are miniaturized

Engineering Contradiction:
Improvepatterning capabilityVSAvoidpattern stability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent introduces a photosensitivity assisting layer as an intermediary between the EUV light source and the photoresist film. This layer absorbs EUV light and generates secondary electrons that penetrate the photoresist film, enabling effective patterning while reducing the direct light exposure that causes pattern collapse. The intermediary layer thus mediates between the need for high-resolution patterning and the need to prevent pattern deformation.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces direct optical exposure (mechanical/electromagnetic system) with a secondary electron-based exposure mechanism. By using the photosensitivity assisting layer to convert EUV light into secondary electrons, the system substitutes direct light action on the photoresist with indirect electron-mediated action, reducing the harmful effects of direct EUV exposure while maintaining patterning effectiveness.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Productivity

If direct light exposure is used for patterning, then patterning efficiency is maintained, but pattern collapse occurs

Engineering Contradiction:
Improvepatterning efficiencyVSAvoidpattern clarity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The photosensitivity assisting layer serves as a mediator that converts EUV light into secondary electrons, which then expose the photoresist film. This indirect exposure mechanism maintains patterning efficiency while improving pattern clarity by avoiding direct EUV light exposure that causes pattern collapse. The intermediary layer enables the system to achieve both high productivity and high manufacturing precision.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If more light is used for exposure, then patterning completeness is improved, but pattern collapse increases

Engineering Contradiction:
Improvepatterning completenessVSAvoidpattern stability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent substitutes direct light exposure with secondary electron exposure by introducing the photosensitivity assisting layer. This substitution allows achieving complete patterning through electron-mediated exposure while avoiding the pattern collapse associated with increased direct light exposure. The secondary electrons provide sufficient exposure energy without the harmful effects of intense EUV light.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the formation of clear micropatterns without pattern collapse, using secondary electrons in addition to direct light exposure, reducing the amount of light required and improving pattern clarity.

Implementation Method 1

utilizing secondary electrons excited by EUV light

Methodology Applied
Scientific EffectPhotoelectric Effect: Photoelectric Effect

Implementation Method 2

uses secondary electrons in addition to direct light exposure

Methodology Applied
Scientific EffectSecondary electron emission: Electron Impact Desorption

Implementation Method 3

the adhesive layer forming a covalent bond with the hydrophilic group

Methodology Applied
Scientific EffectCovalent bonding: Chemical Bonding

Data Source

PatentUS10916437B2Methods of forming micropatterns and substrate processing apparatus
Publication Date: 2021.02.09 SAMSUNG ELECTRONICS CO LTD
  • US10916437B2 patent drawing
  • US10916437B2 patent drawing
  • US10916437B2 patent drawing

AI summary

Provided herein is a method of forming micropatterns, including: forming an etching target film on a substrate; forming a photosensitivity assisting layer on the etching target film, the photosensitivity assisting layer being terminated with a hydrophilic group; forming an adhesive layer on the photosensitivity assisting layer, the adhesive layer forming a covalent bond with the hydrophilic group; forming a hydrophobic photoresist film on the adhesive layer; and patterning the photoresist film.