EUV Optical Element Laser Treatment for Uniform Reflectivity

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Solution Overview

Problem

Existing methods for treating optical elements in the EUV wavelength range face challenges such as reflectivity suppression and compaction, with conventional mirrors being ineffective and current processing techniques leading to unwanted structural displacements and non-homogeneous reflectivity.

Innovation Solution

A method involving pulsed laser irradiation with pulse sequences, where each pulse is separated by 100 ns or less, is used to modify optical elements, allowing for controlled reflectivity adjustments and minimizing structural displacements by exploiting the different timescales of electron and lattice heating.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If backside illumination is used to treat multilayer systems, then immunity to pattern load is achieved, but high intensities cause multilayer compaction and registration impact

Engineering Contradiction:
Improveimmunity to pattern loadVSAvoidregistration accuracy
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies periodic pulsed laser illumination to treat the multilayer system. By using periodic pulses instead of continuous high-intensity illumination, the method achieves the desired modification while allowing thermal diffusion between pulses, thereby reducing compaction and registration errors associated with sustained high-intensity exposure.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent changes the temporal parameters of laser illumination by introducing pulse sequences with specific duty cycles and repetition rates. This parameter modification enables the treatment to proceed at lower average intensities, reducing harmful thermal effects while maintaining effectiveness through cumulative exposure.

Inventive Principle:
Principle #35Parameter changes

2Length of stationary object

If high intensity laser irradiation is applied to modify optical elements, then modification depth is increased, but structural compaction and unwanted side effects increase

Engineering Contradiction:
Improvemodification depthVSAvoidmultilayer compaction
Core Design Contradiction:
Length of stationary objectVSObject-generated harmful factors

Solution Approach 1:

The patent employs periodic pulsed illumination where the laser is turned on and off in cycles. During the off periods, thermal diffusion allows heat to penetrate deeper into the multilayer structure without causing surface compaction. This periodic action enables deep modification while avoiding the harmful side effects of continuous high-intensity irradiation.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent maintains continuous useful action through high repetition rate pulsing, where pulses are delivered so frequently that the cumulative effect achieves deep modification. The short intervals between pulses ensure continuous energy deposition while allowing brief thermal relaxation periods, maintaining treatment effectiveness without excessive compaction.

Inventive Principle:
Principle #20Continuity of useful action

3Device complexity

If conventional mirrors are used for EUV wavelengths, then simplicity of structure is maintained, but reflectance becomes negligible

Engineering Contradiction:
Improvemirror structure simplicityVSAvoidEUV reflectance
Core Design Contradiction:
Device complexityVSLoss of energy

Solution Approach 1:

The patent employs composite multilayer structures consisting of alternating layers of materials with different refractive indices for EUV wavelengths. This composite approach replaces simple conventional mirrors, achieving high EUV reflectance through constructive interference while maintaining a manageable structural complexity through systematic layering.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the optical parameters by using materials specifically selected for their refractive index properties at EUV wavelengths. The layer thicknesses are precisely controlled to satisfy Bragg's law for constructive interference, transforming the optical response from negligible reflectance to high reflectance through parameter optimization.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If frontside illumination is used to treat multilayer systems, then pattern load influence is avoided, but reflectivity suppression increases

Engineering Contradiction:
Improveprocess reproducibilityVSAvoidreflectivity
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent applies periodic pulsed illumination from the frontside, using the off-periods between pulses to allow thermal diffusion and reduce cumulative heating effects. This periodic approach maintains process reproducibility by avoiding pattern load influence while mitigating reflectivity suppression through reduced thermal accumulation.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent modifies the illumination parameters by using lower average intensity achieved through pulsing, which reduces thermal effects and reflectivity suppression. The duty cycle and repetition rate are optimized to maintain treatment effectiveness while minimizing energy loss through reduced continuous exposure.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves homogeneous reflectivity variations of 1% or less and reduces unwanted structural shifts, improving critical dimension control and accuracy in photolithography masks.

Implementation Method 1

exploiting the different timescales of electron and lattice heating

Methodology Applied
Scientific EffectElectron heating:

Implementation Method 2

exploiting the different timescales of electron and lattice heating

Methodology Applied
Scientific EffectLattice heating:

Implementation Method 3

providing a pulsed laser irradiation, wherein the pulsed laser irradiation comprises a plurality of pulse sequences, each pulse sequence comprising a plurality of pulses, wherein a first pulse and a second pulse of the plurality of pulses are separated by a time of 100 ns or less

Methodology Applied
Scientific EffectLaser heating: Laser

Data Source

PatentUS20250237960A1Methods, computer programs and apparatuses for treating an optical element for the extreme ultraviolet wavelength range
Publication Date: 2025.07.24 CARL ZEISS SMS GMBH
  • US20250237960A1 patent drawing
  • US20250237960A1 patent drawing
  • US20250237960A1 patent drawing

AI summary

A method for treating an optical element for the extreme ultraviolet (EUV) wavelength range, the method comprises providing a pulsed laser irradiation, wherein the pulsed laser irradiation comprises a plurality of pulse sequences, each pulse sequence comprising a plurality of pulses, wherein a first pulse and a second pulse of the plurality of pulses are separated by a time of 100 ns or less, and directing the laser irradiation onto the optical element for the EUV wavelength range.