EUV Pellicle Drying via Supernatant Layer

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Solution Overview

Problem

Conventional methods fail to effectively and consistently fabricate ultra-thin, large-area EUV pellicles due to the challenges of managing mechanical stability during drying, particularly the capillary force exerted on the pellicle membrane when withdrawing it from a rinse bath.

Innovation Solution

A method involving the formation of a supernatant polar organic layer with lower surface tension than the rinse bath solution, allowing the EUV pellicle to be withdrawn through this layer during drying, which reduces capillary forces and prevents membrane breakage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional drying methods are used to withdraw the pellicle from the rinse bath, then the pellicle can be dried, but the capillary force breaks the ultra-thin pellicle membrane

Engineering Contradiction:
Improvepellicle integrityVSAvoidcapillary force
Core Design Contradiction:
ReliabilityVSForce

Solution Approach 1:

A supernatant polar organic layer is introduced as an intermediary between the rinse bath and the pellicle during withdrawal. This organic layer has lower surface tension than the rinse bath, creating a gentler capillary force that prevents breaking of the ultra-thin pellicle membrane while still enabling effective drying.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Force

If the surface tension of the drying liquid is minimized, then capillary forces are reduced, but conventional methods require volumetric changes or specialty chemicals that cannot consistently fabricate ultra-thin, large-area EUV pellicles

Engineering Contradiction:
Improvecapillary forceVSAvoidpellicle fabrication consistency
Core Design Contradiction:
ForceVSManufacturing precision

Solution Approach 1:

The surface tension parameter of the drying liquid is changed by using a polar organic layer with lower surface tension than the rinse bath. This parameter change reduces capillary forces to a level that prevents pellicle breakage while maintaining manufacturing precision for ultra-thin, large-area EUV pellicles.

Inventive Principle:
Principle #35Parameter changes

3Loss of time

If the pellicle is withdrawn quickly from the rinse bath, then drying time is reduced, but the capillary force still has time to break the fragile membrane

Engineering Contradiction:
Improvedrying timeVSAvoidmembrane strength
Core Design Contradiction:
Loss of timeVSStrength

Solution Approach 1:

The supernatant polar organic layer serves as a protective intermediary during the withdrawal process. It allows the pellicle to be withdrawn at controlled speeds while the lower surface tension of the organic layer prevents capillary forces from breaking the fragile membrane, thus reducing drying time without compromising membrane strength.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the successful drying of EUV pellicles without damage, maintaining their mechanical stability and preventing residue deposition, thus facilitating the production of high-quality EUV pellicles for semiconductor fabrication.

Implementation Method 1

A top layer is formed above the rinse bath solution, the top layer having a lower surface tension than the rinse bath

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 2

Such capillary force is operative at the liquid-gas-solid boundary on both sides of the partially immersed membrane, and may result in a downward pulling force

Methodology Applied
Scientific EffectCapillary force: Capillary Pressure

Data Source

PatentUS9950349B2Drying an extreme ultraviolet (EUV) pellicle
Publication Date: 2018.04.24 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US9950349B2 patent drawing
  • US9950349B2 patent drawing
  • US9950349B2 patent drawing

AI summary

Systems and methods for rinsing one or more pellicles during fabrication, including immersing and soaking the one or more pellicles in a rinse bath solution for a particular time period, forming a top layer above the rinse bath solution, the top layer having a lower surface tension than the rinse bath, and withdrawing the one or more pellicles through the top layer for drying.