EUV Pellicle Film Dust Prevention via Preliminary Cleaning

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Solution Overview

Problem

The production of pellicle films for extreme ultraviolet lithography is challenged by contamination during trimming and other processes, as the films are extremely thin and prone to breakage, and conventional methods like stealth dicing do not effectively prevent particle attachment.

Innovation Solution

A method involving forming holes in the substrate and pellicle film using an ultra-short pulse laser, followed by trimming and cleaning before removing the substrate, to minimize dust attachment and ensure a high-quality pellicle film.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Shape

If trimming is performed on the pellicle film, then the pellicle film can be shaped correctly, but particles are generated and accumulated on the film surface causing contamination

Engineering Contradiction:
Improvepellicle film shapeVSAvoiddust attachment
Core Design Contradiction:
ShapeVSObject-affected harmful factors

Solution Approach 1:

The patent applies preliminary action by performing cleaning operations before the trimming step. Specifically, the pellicle film is cleaned using a吹扫装置 (blow-off device) with inert gas or plasma before trimming is performed. This removes particles from the film surface in advance, so that when trimming generates particles, they are less likely to adhere to the film surface, thus resolving the contradiction between shaping the film and preventing contamination.

Inventive Principle:
Principle #10Preliminary action

2Ease of operation

If the substrate is removed after trimming, then the pellicle film can be released from the substrate, but particles generated during trimming remain on the film surface

Engineering Contradiction:
Improvepellicle film releaseVSAvoidfilm purity
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The patent performs cleaning actions before substrate removal. The吹扫装置 is used to blow off particles from the pellicle film surface before the substrate is removed. This ensures that the film is clean prior to release, and when the substrate is removed, no particles are generated during this step that would contaminate the film, thus achieving both easy release and high film purity.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses an inert atmosphere (nitrogen or argon gas) in the cleaning process to prevent oxidation and contamination during the cleaning and substrate removal steps. The吹扫装置 introduces inert gas to create a clean environment, preventing external contamination while removing existing particles, thus maintaining film purity during the release process.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

3Object-affected harmful factors

If cleaning is performed after trimming, then dust can be removed from the film surface, but the extremely thin film may be broken

Engineering Contradiction:
Improvedust attachmentVSAvoidfilm strength
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent performs cleaning before trimming rather than after. By removing particles from the film surface before the trimming step, the film is cleaned when it still has substrate support and is more robust. This preliminary cleaning avoids the risk of breaking the extremely thin film during subsequent cleaning operations after trimming, thus resolving the contradiction between removing dust and maintaining film strength.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses inert gas (nitrogen or argon) in the cleaning process to provide a controlled environment that prevents oxidation and minimizes mechanical stress on the thin film. The inert atmosphere allows gentle cleaning without introducing moisture or oxygen that could damage the film, thus removing dust while preserving film integrity.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

4Object-generated harmful factors

If stealth dicing is used for trimming, then particle generation is reduced, but particles still occur during expansion and attach to the pellicle film

Engineering Contradiction:
Improveparticle generationVSAvoiddust attachment
Core Design Contradiction:
Object-generated harmful factorsVSObject-affected harmful factors

Solution Approach 1:

The patent applies preliminary cleaning before trimming, regardless of the trimming method used. Even when stealth dicing is used to minimize particle generation during trimming, the preliminary吹扫 cleaning removes particles from the film surface in advance. This ensures that any particles generated during expansion or trimming will not adhere to the film, thus resolving the contradiction between reducing particle generation and preventing dust attachment.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces dust attachment to the pellicle film, producing a high-quality pellicle with minimized contamination, even for extremely thin EUV films, by performing critical steps before substrate removal.

Implementation Method 1

forming holes in the substrate and the pellicle film with an ultra-short pulse laser

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Data Source

PatentEP3264175B1Method for producing a pellicle
Publication Date: 2020.01.08 MITSUI CHEMICALS INC
  • EP3264175B1 patent drawingFigure 1
  • EP3264175B1 patent drawingFigure 2(a)~2(b)
  • EP3264175B1 patent drawingFigure 3(a)~3(c)

AI summary

A pellicle is contaminated with dust or the like for various reasons during the production thereof. Especially, there is a problem that the risk that the dust or the like is attached is high during trimming or various other processes performed on a pellicle film. The present invention provides a method for producing a pellicle for EUV that decreases the attachment of dust or the like. A method for producing a pellicle includes forming a pellicle film on a substrate; trimming the substrate; and removing at least a part of the substrate after trimming the substrate. Before the part of the substrate is removed, at least particles attached to a surface of the pellicle film are removed.