EUV Photomask Capping Structure for Low-Stray Reflective Openings

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Solution Overview

Problem

Existing EUV photomasks face issues with damage to the reflective multilayer sidewalls and high reflectivity of silicon dioxide capping layers, leading to undesirable stray reflections and reduced effectiveness in EUV lithography processes.

Innovation Solution

The use of a silicon dioxide capping layer is replaced with a protective layer made of materials like ruthenium or ruthenium alloys to prevent oxidation and enhance durability, combined with a sacrificial layer and protective layers on the sidewalls to maintain reflectivity and prevent damage during photomask manufacturing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a silicon dioxide capping layer is used to protect the reflective multilayer, then oxidation protection is provided, but high reflectivity causes undesirable stray reflections

Engineering Contradiction:
Improveoxidation protectionVSAvoidstray reflections
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the material parameter of the capping layer from silicon dioxide to ruthenium or ruthenium alloys, which have different optical properties including lower reflectivity in the EUV range, thereby eliminating stray reflections while maintaining protective functions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite structure with multiple layers including ruthenium-based capping layer, absorber layer, and optional intermediate layers, where each layer is specifically designed to address different functional requirements simultaneously

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If the reflective multilayer sidewalls are exposed during manufacturing, then manufacturing simplicity is maintained, but sidewall damage occurs reducing service life

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidservice life
Core Design Contradiction:
Ease of manufactureVSDuration of action of stationary object

Solution Approach 1:

The patent applies a protective capping layer of ruthenium or ruthenium alloy over the reflective multilayer before manufacturing processes, providing preliminary protection against oxidation and damage during subsequent manufacturing steps

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The ruthenium-based capping layer serves as a cushioning protective barrier that prevents direct exposure of the fragile reflective multilayer sidewalls to damaging environments during manufacturing and operation

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Reliability

If ruthenium or ruthenium alloy protective layers are applied, then durability and oxidation resistance are enhanced, but manufacturing complexity increases

Engineering Contradiction:
ImprovedurabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses a thin-film ruthenium or ruthenium alloy capping layer that can be deposited using standard sputtering techniques, providing effective protection at minimal material cost and thickness

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The protective layers effectively prevent damage to the reflective multilayer sidewalls, maintaining high reflectivity and extending the service life of the EUV photomask, thereby enhancing the performance and reliability of EUV lithography processes.

Implementation Method 1

The use of a silicon dioxide capping layer is replaced with a protective layer made of materials like ruthenium or ruthenium alloys to prevent oxidation

Methodology Applied
Scientific EffectOxidation prevention: Oxidation

Implementation Method 2

maintaining high reflectivity and extending the service life of the EUV photomask

Methodology Applied
Scientific EffectReflectivity maintenance: Reflection

Data Source

PatentUS20250383595A1EUV photomasks and manufacturing method thereof
Publication Date: 2025.12.18 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US20250383595A1 patent drawing
  • US20250383595A1 patent drawing
  • US20250383595A1 patent drawing

AI summary

A method of manufacturing a reflective mask includes forming a sacrificial layer over a substrate and forming a reflective multilayer over the sacrificial layer. A capping layer is formed over the reflective multilayer. An absorber layer is formed over the capping layer. An opening is formed in the absorber layer, the capping layer, and the reflective layer exposing a portion of the sacrificial layer, and a protective layer is formed along sidewalls of the opening. The protective layer is made of material from the sacrificial layer.