EUV Reflective Mask Blank Phase Optimization

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing reflective masks for EUV lithography face challenges in achieving high dimension accuracy for fine line-like patterns due to shadowing effects and limitations in optimizing reflectance and phase difference based on exposure conditions and pattern complexity.

Innovation Solution

A reflective mask blank with a multi-layer reflection film and an absorption layer, where the absorption layer has a refractive index of 0.930 or less and an extinction coefficient of 0.025 or more, and a phase difference of 220 to 280°, is used to enhance the reflectance and phase shift properties, thereby improving the accuracy of fine line-like patterns.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If the thickness of the absorption layer is increased to improve phase shift effect, then the phase difference increases, but dimension error due to shadowing increases

Engineering Contradiction:
Improvedimension accuracyVSAvoidshadowing effect
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the optical parameters (refractive index and extinction coefficient) of the absorption layer material to achieve the desired phase difference while maintaining thin thickness. By selecting materials with specific optical properties, the phase shift effect is enhanced without increasing thickness, thereby avoiding shadowing effects.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite material structures combining the multi-layer reflection film with the absorption layer having specific optical properties. This composite structure achieves both high reflectance and appropriate phase difference while keeping the absorption layer thin to minimize shadowing.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If the absorption layer thickness is decreased to suppress shadowing, then shadowing effect is reduced, but phase difference decreases

Engineering Contradiction:
Improveshadowing effectVSAvoiddimension accuracy
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

The patent compensates for reduced thickness by carefully selecting materials with optimized refractive index and extinction coefficient values. This allows the thin absorption layer to still produce the necessary phase difference for high dimension accuracy while maintaining thinness to suppress shadowing.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If the phase difference is optimized for 180° or 216° based on conventional designs, then transmissive mask performance is improved, but reflective mask performance for oblique incidence is insufficient

Engineering Contradiction:
Improvetransfer accuracyVSAvoidsuitability for oblique incidence
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The patent adjusts the target phase difference parameter from conventional 180° or 216° to approximately 252° specifically for oblique incidence conditions in reflective masks. This parameter change optimizes the interference pattern for the specific application, achieving high transfer accuracy for reflective EUV lithography.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution enables the formation of transfer patterns with high dimension accuracy for fine line-like patterns, effectively addressing the limitations of existing technologies by optimizing the reflectance and phase difference within the absorption layer.

Implementation Method 1

an absorption layer that absorbs EUV light

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Implementation Method 2

reflect light such that it differs in phase from reflected light from a multi-layer reflection film

Methodology Applied
Scientific EffectPhase shift: Phase Change

Implementation Method 3

a multi-layer reflection film that reflects EUV light

Methodology Applied
Scientific EffectReflection: Reflection

Implementation Method 4

a substance or shape different in refractive index and transmittance from the transmission portion is added to change the phase of the transmitted light

Methodology Applied
Scientific EffectRefraction: Refraction

Data Source

PatentUS20250172863A1Reflective mask blank and reflective mask
Publication Date: 2025.05.29 AGC INC
  • US20250172863A1 patent drawing
  • US20250172863A1 patent drawing
  • US20250172863A1 patent drawing

AI summary

A reflective mask blank 10 for EUV lithography in which a multi-layer reflection film 2 that reflects EUV light and an absorption layer 3 that absorbs EUV light are laminated on a substrate 1 in the stated order from the substrate 1 side, wherein the absorption layer 3 has a refractive index of 0.930 or less and an extinction coefficient of 0.025 or more for EUV light having a wavelength of 13.5 nm, and a phase difference between reflected light from a surface of the multi-layer reflection film and reflected light from a surface of the absorption layer with respect to an incident ray of the EUV light having a wavelength of 13.5 nm is 220 to 280°, and a reflective mask in which a mask pattern is formed on the absorption layer 3.