EUV Spectral Purity Optical Element with Absorptive Layer

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Solution Overview

Problem

Conventional reflective grazing-incidence spectral purity filters are ineffective in suppressing 10.6 μm radiation in Laser Produced Plasma (LPP) Extreme Ultraviolet (EUV) sources due to low reflectivity of AR coatings for EUV and the tendency of conventional mirror substrates to reflect rather than absorb this radiation.

Innovation Solution

An optical element comprising a first layer reflective for EUV radiation, a second layer absorptive for 10.6 μm radiation, and a third layer transparent for both, with the first layer positioned upstream to improve spectral purity by absorbing or scattering unwanted radiation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional reflective grazing-incidence spectral purity filter with AR coating is used, then EUV radiation is reflected, but 10.6 μm radiation is also reflected instead of being absorbed

Engineering Contradiction:
Improvespectral purityVSAvoidunwanted heating of wafer
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The optical element is segmented into multiple functional layers: a first layer for EUV reflection, a second layer for 10.6 μm absorption, and a third layer for mechanical support. This segmentation allows each layer to perform its specific function optimally without interfering with others.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different layers are assigned different material properties tailored to specific wavelength requirements. The first layer has high EUV reflectivity, the second layer has high 10.6 μm absorptivity, and the third layer provides mechanical strength. This local quality differentiation resolves the contradiction by making the optical element selectively interactive with different radiation types.

Inventive Principle:
Principle #3Local quality

2Use of energy by moving object

If an AR coating with high EUV reflectivity is used, then EUV radiation is effectively reflected, but the coating has very low reflectivity for 10.6 μm radiation

Engineering Contradiction:
ImproveEUV radiation utilizationVSAvoidtransmission of unwanted 10.6 μm radiation
Core Design Contradiction:
Use of energy by moving objectVSObject-affected harmful factors

Solution Approach 1:

The second layer acts as an intermediary between the first and third layers, specifically designed to absorb 10.6 μm radiation that passes through the first layer. This intermediary layer prevents the harmful radiation from reaching the substrate while not affecting the EUV reflection function of the first layer.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The optical element uses a composite structure combining materials with different optical properties: a reflective material for EUV, an absorptive material for 10.6 μm, and a transparent support material. This composite approach allows simultaneous optimization for multiple wavelength requirements.

Inventive Principle:
Principle #40Composite materials

3Ease of operation

If conventional mirror substrates are used, then they reflect 10.6 μm radiation, but this reflection is insufficient for spectral purity requirements

Engineering Contradiction:
Improveoptical performanceVSAvoidspectral purity
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The invention changes the material parameter of the second layer from conventional reflective materials to specifically absorptive materials for 10.6 μm radiation. This parameter change transforms the optical interaction from reflection to absorption, achieving the required spectral purity while maintaining mechanical functionality.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly enhances spectral purity by reducing reflection of 10.6 μm radiation while maintaining high EUV reflectivity, thereby minimizing unwanted heating of the wafer and improving the overall performance of EUV lithography tools.

Implementation Method 1

a first layer (4) comprising a first material, the first layer being configured to be reflective for radiation of a first wavelength

Methodology Applied
Scientific EffectReflection: Reflection

Implementation Method 2

the first layer being configured to be at least partially transparent for radiation of a second wavelength

Methodology Applied
Scientific EffectSelective transmission:

Implementation Method 3

a second layer (2) comprising a second material, the second layer being configured to be substantially absorptive for the radiation of the second wavelength

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Implementation Method 4

the first layer being located upstream in the optical path of incoming radiation with respect to the second layer in order to improve spectral purity of the radiation of the first wavelength

Methodology Applied
Scientific EffectSpectral filtering: Filter (optical)

Data Source

PatentUS8345223B2Optical element, lithographic apparatus including such an optical element, device manufacturing method, and device manufactured thereby
Publication Date: 2013.01.01 ASML NETHERLANDS BV
  • US8345223B2 patent drawing
  • US8345223B2 patent drawing
  • US8345223B2 patent drawing

AI summary

An optical element includes a first layer that includes a first material, and is configured to be substantially reflective for radiation of a first wavelength and substantially transparent for radiation of a second wavelength. The optical element includes a second layer that includes a second material, and is configured to be substantially absorptive or transparent for the radiation of the second wavelength. The optical element includes a third layer that includes a third material between the first layer and the second layer, and is substantially transparent for the radiation of the second wavelength and configured to reduce reflection of the radiation of the second wavelength from a top surface of the second layer facing the first layer. The first layer is located upstream in the optical path of incoming radiation with respect to the second layer in order to improve spectral purity of the radiation of the first wavelength.