EVOH Multilayer Film Balancing Gas Barrier and Flexibility

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing reaction apparatus containers, particularly those with stirring blades, face issues with deformation leading to pinhole formation, compromising gas barrier properties due to inadequate bending resistance and flexibility, and handleability is poor when flexibility is too high or too low.

Innovation Solution

A multilayer film comprising a layer of ethylene-vinyl alcohol copolymer (EVOH) and a thermoplastic resin, with specific thickness and elastic modulus ratios, ensuring a balance of gas barrier properties, bending resistance, and flexibility, and a reaction apparatus incorporating this film with a stirring blade.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a multilayer film with EVOH layer is used to improve gas barrier properties, then oxygen transmission resistance is improved, but bending resistance is insufficient causing pinhole formation

Engineering Contradiction:
Improvegas barrier propertiesVSAvoidbending resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies composite materials by creating a multilayer film structure combining EVOH (for gas barrier) with thermoplastic resin layers (for bending resistance and flexibility). Specifically, Claim 1 defines a multilayer film with at least one EVOH layer (A) and at least one thermoplastic resin layer (B), where the composite structure integrates the strengths of different materials to simultaneously achieve gas barrier properties and bending resistance without pinhole formation during stirring operations.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If the flexibility of the container is increased to improve handleability, then ease of operation is improved, but deformation occurs leading to pinhole generation

Engineering Contradiction:
ImprovehandleabilityVSAvoidgas barrier properties
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent applies local quality by creating a multilayer structure where different layers have different mechanical properties. The EVOH layer (A) provides gas barrier properties, while the thermoplastic resin layer (B) provides flexibility and bending resistance. This local differentiation of material properties within the composite structure allows the container to be both flexible enough for handling and resistant enough to prevent pinhole formation during stirring operations.

Inventive Principle:
Principle #3Local quality

3Strength

If the flexibility of the container is decreased to improve bending resistance, then strength is improved, but handleability deteriorates

Engineering Contradiction:
Improvebending resistanceVSAvoidhandleability
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent resolves this contradiction through composite materials where the thermoplastic resin layer (B) is specifically designed to provide both the required bending resistance and flexibility. The composite structure allows the container to maintain high bending resistance to prevent pinholes while retaining sufficient flexibility for easy handling, as each layer contributes its specific mechanical properties to the overall performance.

Inventive Principle:
Principle #40Composite materials

Data Source

PatentEP4606569A1Multilayer film, packaging material, and reaction apparatus
Publication Date: 2025.08.27 KURARAY CO LTD
  • EP4606569A1 patent drawing
  • EP4606569A1 patent drawing
  • EP4606569A1 patent drawing

AI summary

Provided is a multilayer film being favorable in gas barrier properties and bending resistance, and having appropriate flexibility; and a packaging material and a reaction apparatus including such a multilayer film. The multilayer film includes: at least one layer (A) containing an EVOH as a principal component; and at least one layer (B) containing, as a principal component, a thermoplastic resin other than the EVOH. A proportion of a total thickness of the at least one layer (A) and the at least one layer (B) to a total thickness of all layers is 90% or more. The multilayer film satisfies the following inequality (1) and the like. 0.0006≦LALB⋅1Et≦0.003⋯ In the inequality (1): LA represents a total thickness of the at least one layer (A); LB represents a total thickness of the at least one layer (B); and Et represents an ethylene unit content (mol%) in the EVOH.