Light-emitting Element Exciplex Host-Guest Fluorescence

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Solution Overview

Problem

Current light-emitting elements face challenges in achieving high emission efficiency, particularly in developing stable compounds for blue light emission and white light emission using fluorescent materials, due to issues with triplet excited energy levels and manufacturing costs associated with phosphorescent compounds like platinum group organometallic complexes.

Innovation Solution

A light-emitting element is designed with a structure that includes an exciplex formed in a light-emitting layer, where triplet excitons are converted into singlet excitons through triplet-triplet annihilation, allowing for efficient energy transfer and high emission efficiency using a combination of fluorescent materials in a small number of deposited layers, reducing manufacturing complexity and cost.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If phosphorescent compounds are used to achieve high emission efficiency, then emission efficiency is improved, but manufacturing cost increases due to platinum group organometallic complexes

Engineering Contradiction:
Improveemission efficiencyVSAvoidmanufacturing cost
Core Design Contradiction:
Loss of energyVSEase of manufacture

Solution Approach 1:

The patent replaces expensive phosphorescent compounds containing platinum group metals with inexpensive fluorescent organic compounds. These fluorescent materials, while having shorter lifetimes, provide comparable emission efficiency at a fraction of the cost, eliminating dependence on scarce and expensive platinum group elements.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the fundamental emission mechanism parameter from phosphorescence to fluorescence. By selecting fluorescent compounds with appropriate energy levels and optimizing the host-guest system, the patent achieves high emission efficiency through fluorescence rather than phosphorescence, thereby avoiding the use of expensive phosphorescent materials.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If fluorescent compounds are used instead of phosphorescent compounds, then manufacturing cost is reduced, but emission efficiency decreases due to triplet excited state limitations

Engineering Contradiction:
Improvemanufacturing costVSAvoidemission efficiency
Core Design Contradiction:
Ease of manufactureVSLoss of energy

Solution Approach 1:

The patent introduces a host material as an intermediary system that facilitates efficient energy transfer to the fluorescent guest compounds. The host-guest energy transfer mechanism ensures that triplet excited states are effectively converted to singlet states that can emit fluorescence, thereby maintaining high emission efficiency with inexpensive fluorescent materials.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs composite host-guest material systems where the host material provides the structural framework and energy transfer pathways, while the fluorescent guest compounds provide the emission function. This composite approach optimizes both the efficiency of energy utilization and the cost-effectiveness of the light-emitting layer.

Inventive Principle:
Principle #40Composite materials

3Illumination intensity

If multiple EL layers are stacked to achieve white light emission, then light emission quality is improved, but device complexity increases

Engineering Contradiction:
Improvelight emission qualityVSAvoiddevice complexity
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The patent merges multiple light-emitting functions into a single EL layer by co-doping fluorescent compounds that emit different colors (e.g., blue and yellow-green). This single-layer approach produces white light emission while avoiding the manufacturing complexity and alignment issues associated with stacking multiple separate EL layers.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent creates a multi-functional single EL layer that simultaneously performs the roles of multiple layers would traditionally play. By incorporating fluorescent compounds with complementary emission spectra into one layer, the system achieves white light emission, color tuning capability, and efficient electroluminescence all in a single structural unit.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables a light-emitting element with high emission efficiency, low power consumption, and simplified manufacturing, achieving efficient conversion of triplet excitons to singlet excitons for enhanced light emission, particularly in blue and white light applications.

Implementation Method 1

triplet excitons are converted into singlet excitons through triplet-triplet annihilation

Methodology Applied
Scientific EffectTriplet-triplet annihilation:

Implementation Method 2

research and development have been extensively conducted on light-emitting elements using electroluminescence (EL)

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 3

Light emission from the singlet excited state is referred to as fluorescence

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Implementation Method 4

Light emission from the triplet excited state is referred to as phosphorescence

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Data Source

PatentUS10461271B2Light-emitting element, display device, electronic device, and lighting device
Publication Date: 2019.10.29 SEMICON ENERGY LAB CO LTD
  • US10461271B2 patent drawing
  • US10461271B2 patent drawing
  • US10461271B2 patent drawing

AI summary

A light-emitting element with high emission efficiency which includes fluorescent materials is provided. The light-emitting element includes a first light-emitting layer and a second light-emitting layer. The first light-emitting layer includes a first fluorescent material and a first host material, and the second light-emitting layer includes a second fluorescent material and a second host material. The second host material includes a first organic compound and a second organic compound. The first organic compound and the second organic compound form an exciplex. A singlet excited energy level of the first host material is higher than a singlet excited energy level of the first fluorescent material, and a triplet excited energy level of the first host material is lower than a triplet excited energy level of the first fluorescent material.