Exhaust Gas Control Catalyst Porosity Optimization

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Solution Overview

Problem

Existing exhaust gas control apparatuses with catalysts on filters with a wall flow structure face challenges in achieving optimal exhaust gas control performance due to improper porosity of the catalyst layers, leading to inadequate reaction of exhaust gas with the catalyst and reduced efficiency in removing harmful components like NOx.

Innovation Solution

The exhaust gas control apparatus includes a honeycomb substrate with an inlet cell-side catalyst layer having a specific porosity range (0.1% to 8%) and a pore-forming material content (1 wt % to 3 wt %) to enhance diffusion and contact time of exhaust gas with the catalyst, while the outlet cell-side catalyst layer extends from the outlet-side end of the partition wall to improve overall performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the porosity of the inlet cell-side catalyst layer is increased to enhance diffusion of exhaust gas, then the contact time between exhaust gas and catalyst is improved, but the structural strength and stability of the catalyst layer deteriorates

Engineering Contradiction:
Improveexhaust gas control performanceVSAvoidcatalyst layer strength
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent applies parameter changes by precisely controlling the porosity of the inlet cell-side catalyst layer within the range of 0.1% to 8%. This optimization balances the need for sufficient exhaust gas diffusion to maintain high exhaust gas control performance while ensuring the catalyst layer retains adequate structural strength and stability for durable operation.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If the porosity of the inlet cell-side catalyst layer is increased to improve diffusion, then the reaction efficiency improves, but the pressure loss increases

Engineering Contradiction:
Improvereaction efficiencyVSAvoidpressure loss
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The patent optimizes the porosity parameter of the inlet cell-side catalyst layer to fall within 0.1% to 8%, achieving a balance where sufficient diffusion occurs to maintain high reaction efficiency while limiting excessive porosity that would cause increased pressure loss and energy waste.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If the pore-forming material content is increased to create optimal porosity, then the diffusion of exhaust gas is enhanced, but the manufacturing complexity increases

Engineering Contradiction:
Improvediffusion efficiencyVSAvoidmanufacturing process complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent specifies a precise pore-forming material content range of 1 wt% to 3 wt% in the inlet cell-side catalyst layer. This parameter control achieves optimal porosity and diffusion efficiency while simplifying the manufacturing process by providing clear, quantifiable specifications for material formulation.

Inventive Principle:
Principle #35Parameter changes

4Productivity

If the catalyst layer porosity is optimized for better exhaust gas contact, then the NOx removal rate increases, but the manufacturing precision requirements increase

Engineering Contradiction:
ImproveNOx removal rateVSAvoidporosity control precision
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent establishes a specific porosity range of 0.1% to 8% for the inlet cell-side catalyst layer, which can be achieved by controlling the pore-forming material content at 1 wt% to 3 wt%. This provides clear manufacturing targets that balance high NOx removal performance with achievable production precision requirements.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration improves the exhaust gas control performance by optimizing the porosity and distribution of the catalyst layers, leading to enhanced NOx removal rates and reduced pressure loss, thereby meeting the required levels for exhaust gas control.

Implementation Method 1

The slurry for forming the inlet cell-side catalyst layer contains 1 wt % to 3 wt % of a pore-forming material based on a total weight of the inlet cell-side catalyst layer... Porosity of the inlet cell-side catalyst layer is 0.1% to 8%... to enhance diffusion and contact time of exhaust gas with the catalyst

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS11473472B2Exhaust gas control apparatus and manufacturing method thereof
Publication Date: 2022.10.18 TOYOTA JIDOSHA KK
  • US11473472B2 patent drawing
  • US11473472B2 patent drawing
  • US11473472B2 patent drawing

AI summary

An exhaust gas control apparatus includes a honeycomb substrate and an inlet cell-side catalyst layer. The honeycomb substrate includes a porous partition wall that defines a plurality of cells extending from an inlet-side end face to an outlet-side end face. The cells include an inlet cell and an outlet cell that are adjacent to each other with the partition wall therebetween. The inlet cell is open at its inlet-side end and is sealed at its outlet-side end. The outlet cell is sealed at its inlet-side end and is open at its outlet-side end. The inlet cell-side catalyst layer is provided on a surface on the inlet cell side of the partition wall and extends from an inlet-side end of the partition wall. Porosity of the inlet cell-side catalyst layer is in a specific range.