Expandable Graphite Textile Insulation for Breathable Heat Protection

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Solution Overview

Problem

Current flame protective clothing for firefighters and industrial workers faces challenges in providing adequate insulation against heat transfer while maintaining breathability, leading to increased heat stress and potential heat casualties.

Innovation Solution

A thermally protective material comprising a flame-resistant, thermally stable textile with a convective barrier and an active insulation of a polymer resin-expandable graphite mixture, which increases in thickness by at least 200% after exposure to high temperatures, enhancing thermal protective performance while maintaining breathability and comfort.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If thermally stable insulative layers are added to provide suitable insulation, then thermal protective performance is improved, but heat stress burden increases

Engineering Contradiction:
Improvethermal protective performanceVSAvoidheat stress burden
Core Design Contradiction:
Object-affected harmful factorsVSTemperature

Solution Approach 1:

The insulation layer dynamically changes its thickness in response to temperature exposure. When exposed to fire or high heat, the intumescent material expands to increase insulation thickness, providing enhanced thermal protection when needed most. During normal conditions, the layer remains thin to minimize heat stress burden during routine operations.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The insulation layer changes its physical parameter (thickness) in response to temperature changes. The intumescent materials undergo a phase transition when exposed to high temperatures, expanding from a thin state to a thick insulating state, thereby adapting the thermal protective performance to the operational conditions.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If insulation thickness is increased to protect from heat transfer, then thermal protective performance is improved, but breathability is compromised

Engineering Contradiction:
Improvethermal protective performanceVSAvoidbreathability
Core Design Contradiction:
Object-affected harmful factorsVSEase of operation

Solution Approach 1:

The insulation layer dynamically adjusts its thickness based on thermal exposure. During normal operations, the thin insulation layer maintains breathability and comfort. When exposed to fire, the layer expands to provide enhanced thermal protection, effectively adapting to the changing operational requirements.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The physical parameter of the insulation layer (thickness) changes in response to temperature exposure. The intumescent materials transform from a thin, breathable state during normal operations to a thick, protective state during fire exposure, optimizing both breathability and thermal protection as needed.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If intumescent materials are applied to textile substrates, then thermal protective performance increases, but manufacturing complexity increases

Engineering Contradiction:
Improvethermal protective performanceVSAvoidmanufacturing complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The intumescent materials are pre-applied to the textile substrates during the manufacturing process, forming a coating that is then cured to create a stable, integrated structure. This preliminary action ensures that the thermal protective performance is built into the garment during production, rather than requiring additional field applications or modifications.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly improves thermal protective performance, reducing the risk of burns and heat stress by increasing the material's thickness and thermal insulation without compromising breathability or comfort, thus enhancing the wearer's ability to perform in high-heat environments.

Implementation Method 1

an active insulation comprising a polymer resin-expandable graphite mixture applied to the convective barrier on a side opposite the flame resistant, thermally stable textile, wherein the thickness of the active insulation increases by at least 200% after 90-seconds in a convective oven heated to 300°C

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 2

a convective barrier bonded to the flame resistant, thermally stable textile

Methodology Applied
Scientific EffectConvection barrier: Convection

Implementation Method 3

protection from flame requires materials that both self-extinguish and prevent burn caused by heat transfer through a garment

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Data Source

PatentEP2209622B1Thermally protective materials
Publication Date: 2013.08.14 GORE ENTERPRISE HOLDINGS INC
  • EP2209622B1 patent drawingFigure 1
  • EP2209622B1 patent drawingFigure 2
  • EP2209622B1 patent drawingFigure 3

AI summary

A mixture comprising an expandable graphite and a polymer resin is described wherein the polymer resin-expandable graphite mixture has a volume increase and structural integrity after exposure to heat. Methods are described for increasing the thermal protective performance (TPP) of textiles and laminates while optionally maintaining comfort, flexibility, and liquid protective properties.