Expanded Graphite Carbon Composite Sealing for Downhole Stability

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Solution Overview

Problem

Current sealing materials for downhole applications, such as elastomers and metals, face limitations in balancing stability, elasticity, and mechanical strength, particularly in harsh environments encountered in heavy oil exploration.

Innovation Solution

A carbon composite is developed by incorporating expanded graphite with a filler, where the filler forms a second phase that bonds the basal planes of expanded graphite particles together, enhancing mechanical strength through thermal diffusion, vapor deposition, or polymer carbonization processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If elastomers are used as sealing materials, then elasticity and conformability are improved, but stability and resistance to decomposition under harsh conditions deteriorate

Engineering Contradiction:
ImproveelasticityVSAvoidstability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent uses expanded graphite as a base material and incorporates filler particles (such as metal oxides, ceramics, or carbides) to create a composite sealing material. This composite structure combines the elasticity and conformability of expanded graphite with the thermal stability and chemical resistance of the filler particles, resolving the contradiction between elasticity and stability under harsh downhole conditions

Inventive Principle:
Principle #40Composite materials

2Reliability

If metals are used as sealing materials, then stability and corrosion resistance are improved, but ductility and elasticity deteriorate

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidductility
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent creates a composite where expanded graphite provides the ductility and elasticity needed for sealing, while dispersed filler particles contribute to corrosion resistance and thermal stability. This approach allows the material to conform to rough casing surfaces like elastomers while maintaining metal-like corrosion resistance

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The filler particles are distributed throughout the expanded graphite matrix, creating local regions with enhanced corrosion resistance while the overall expanded graphite structure maintains its ductility and elasticity. This local reinforcement strategy allows different properties to coexist in different regions of the material

Inventive Principle:
Principle #3Local quality

3Reliability

If carbon materials are used as sealing materials, then thermal stability and flexibility are improved, but mechanical strength deteriorates

Engineering Contradiction:
Improvethermal stabilityVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent incorporates filler particles with high mechanical strength (such as ceramic particles, metal particles, or carbide particles) into the expanded graphite matrix. These filler particles act as reinforcement, improving the overall mechanical strength while the expanded graphite continuous phase maintains thermal stability and flexibility. The synergistic combination resolves the contradiction between thermal stability and mechanical strength

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The carbon composite exhibits improved mechanical strength and stability, making it suitable for demanding downhole applications while maintaining flexibility and conformability.

Implementation Method 1

the filler forms a second phase that bonds the basal planes of expanded graphite particles together, enhancing mechanical strength through thermal diffusion

Methodology Applied
Scientific EffectThermal diffusion: Diffusion

Implementation Method 2

enhancing mechanical strength through thermal diffusion, vapor deposition, or polymer carbonization processes

Methodology Applied
Scientific EffectVapor deposition: Physical Vapour Deposition

Implementation Method 3

enhancing mechanical strength through thermal diffusion, vapor deposition, or polymer carbonization processes

Methodology Applied
Scientific EffectCarbonization: Pyrolysis

Data Source

PatentEP3080047B1Carbon composites and methods of manufacture
Publication Date: 2019.10.02 BAKER HUGHES CO
  • EP3080047B1 patent drawingFigure 1A~1C
  • EP3080047B1 patent drawingFigure 2
  • EP3080047B1 patent drawingFigure 3

AI summary

A carbon composite contains a plurality of expanded graphite particles; and a second phase comprising a carbide, a carbonization product of a polymer, or a combination thereof; wherein the second phase bonds at least two adjacent basal planes of the same expanded graphite particle together. Methods of making the carbon composite and articles comprising the carbon composite are also disclosed.