Expanded Magnet Coating Structure for High-Temperature Corrosion Resistance

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Solution Overview

Problem

Existing expandable coatings for rare earth permanent magnet synchronous motors lack sufficient thermal stability and mechanical performance at high temperatures, leading to potential damage and reduced corrosion resistance under centrifugal forces and high operational temperatures.

Innovation Solution

An expanded coating with a specific microstructure comprising spheroid pores and a filler resin, where the spheroid pores occupy 50%-60% of the cross-sectional area, and a combination of chemical and physical foaming agents is used, providing enhanced thermal stability and mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional expandable coatings are used, then the coating can be expanded by thermal treatment to fill the magnetic steel groove, but the coating lacks sufficient thermal stability and mechanical performance at high temperatures (>150°C), leading to potential damage under centrifugal force

Engineering Contradiction:
Improvethermal stability at high temperatureVSAvoidmechanical strength at high temperature
Core Design Contradiction:
TemperatureVSStrength

Solution Approach 1:

The patent uses a composite coating system comprising an expandable coating layer and a heat-resistant coating layer. The heat-resistant coating layer contains inorganic fillers (alumina, silica, zirconia) and heat-resistant resins that provide thermal stability and mechanical strength at high temperatures, while the expandable coating layer provides expansion capability to fill the magnetic steel groove. This composite structure resolves the contradiction by combining materials with complementary properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the coating composition by incorporating heat-resistant resins (polyimide, phenolic resin, epoxy resin) and inorganic fillers in specific proportions. The weight ratio of inorganic filler to heat-resistant resin is controlled within 9:1 to 1:1, and the total content of heat-resistant resin and inorganic filler is maintained at 80-99.9 wt%. These parameter changes enable the coating to maintain mechanical strength and thermal stability at temperatures above 150°C.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the expanded coating has relatively poor thermal stability, then the coating may be sheared along the magnetic steel groove under centrifugal force, but improving thermal stability is needed to prevent damage

Engineering Contradiction:
Improvecoating integrity under centrifugal forceVSAvoidthermal stability
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The heat-resistant coating layer acts as a protective barrier that prevents the expandable coating from direct exposure to high-temperature environments and centrifugal forces. The inorganic fillers (alumina, silica, zirconia) provide structural integrity and resistance to shear stress, while the heat-resistant resins provide adhesion and flexibility. This composite structure ensures coating integrity under centrifugal force at high temperatures.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies different coating layers with specific local functions: the expandable coating layer provides expansion and filling capability in the groove, while the heat-resistant coating layer provides thermal and mechanical protection on the outer surface. Each layer is optimized for its specific function, with the heat-resistant layer containing higher concentrations of inorganic fillers and heat-resistant resins to handle the harsh operating conditions.

Inventive Principle:
Principle #3Local quality

3Volume of stationary object

If the coating is designed with high expansion capability, then the coating can effectively fill the magnetic steel groove, but the mechanical performance and corrosion resistance at high temperatures need to be improved

Engineering Contradiction:
Improveexpansion volume to fill grooveVSAvoidcorrosion resistance at high temperature
Core Design Contradiction:
Volume of stationary objectVSReliability

Solution Approach 1:

The expandable coating layer contains expandable microspheres that provide high expansion capability to fill the magnetic steel groove effectively. The heat-resistant coating layer containing inorganic fillers and heat-resistant resins provides corrosion resistance and thermal stability. The combination of these two layers resolves the contradiction by allowing the inner layer to expand while the outer layer protects against corrosion and high temperatures.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The expandable coating layer utilizes expandable microspheres that create a porous structure upon expansion, enabling the coating to fill the magnetic steel groove effectively. The porous structure provides high expansion volume while maintaining connectivity with the substrate. The heat-resistant coating layer then seals and protects this porous structure from corrosion and thermal degradation.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating exhibits improved shear strength, tensile strength, oil resistance, and neutral salt spray performance at 170°C, with shear strength greater than 2 MPa and neutral salt spray performance exceeding 288 hours, ensuring durability and reliability in high-temperature environments.

Implementation Method 1

The expandable coatings can be expanded by thermal treatment to fill a magnetic steel groove, thus fixing the magnetic steel pieces

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 2

the expandable powder comprises a prepolymer, a curing agent, at least one functional filler, and a foaming agent

Methodology Applied
Scientific EffectFoaming: Foam

Implementation Method 3

the foaming agent is a chemical foaming agent. The foaming agent does not prematurely react with the substrate of the coating

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 4

the expandable powder comprises a prepolymer, a curing agent

Methodology Applied
Scientific EffectCuring: Chemical Bonding

Implementation Method 5

the expandable coating material comprises a thermosetting resin

Methodology Applied
Scientific EffectCross-linking: Chemical Bonding

Data Source

PatentUS20240101836A1Expanded coating, preparation method and use thereof, and permanent magnet comprising same
Publication Date: 2024.03.28 YANTAI ZHENGHAI MAGNETIC MATERIAL CO LTD
  • US20240101836A1 patent drawing

AI summary

The present disclosure provides an expanded coating, a preparation method and use thereof, and a permanent magnet comprising same. The expanded coating described herein comprises pores and a filler resin arranged among the pores; the pores comprise at least a spheroid pore having a cross section with a long diameter and a short diameter; in the cross section of the expanded coating, the area of the spheroid pores accounts for 50%-60% of the cross-sectional area of the expanded coating. The permanent magnet of the present disclosure comprises the expanded coating. The expanded coating has high strength and can exhibit excellent mechanical properties and corrosion resistance at high temperatures (such as 170° C.), with a shear strength greater than 2 MPa, a tensile strength greater than 2 MPa, an oil resistance greater than 1800 h and a neutral salt spray performance greater than 288 h at 170° C.