Explosion-Powered Supercapacitor for Microsecond Pulse Discharge

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Solution Overview

Problem

Conventional supercapacitors face a limitation in response time due to the slow diffusion of ions in the electrolyte, which is not sufficient for many applications requiring faster charge release.

Innovation Solution

An explosion-powered supercapacitor design is introduced, where porous electrodes are in compressive contact with an explosive charge, allowing the explosion to compress the electrodes and rapidly eject electrolyte, thereby increasing the potential difference and enabling rapid charge discharge.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If supercapacitors use liquid electrolyte with high surface area carbon or metal oxide materials to increase capacitance, then charge storage capacity increases by 6 or more orders of magnitude, but response time increases to milliseconds to seconds due to slow ion diffusion

Engineering Contradiction:
Improvecharge storage capacityVSAvoidresponse time
Core Design Contradiction:
Quantity of substanceVSSpeed

Solution Approach 1:

The invention changes the physical state of the electrolyte from liquid to solid polymer gel, and modifies the electrode structure to composite materials with conductive polymers. These parameter changes transform the ion transport mechanism from slow diffusion in liquid to faster ion mobility in the gel matrix, achieving response times in the microsecond to millisecond range while maintaining high charge storage capacity through the composite electrode structure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite electrode materials combining conductive polymers (such as polyaniline, polythiophene, or polypyrrole) with metal oxides or carbon materials. This composite structure provides both the high surface area needed for charge storage and improved ion transport pathways, resolving the contradiction between high capacitance and fast response time

Inventive Principle:
Principle #40Composite materials

2Speed

If conventional capacitors use parallel metal plates with dielectric material to store charge, then response time is extremely fast (far shorter than microsecond), but charge storage capacity is limited

Engineering Contradiction:
Improveresponse timeVSAvoidcharge storage capacity
Core Design Contradiction:
SpeedVSQuantity of substance

Solution Approach 1:

The invention employs porous electrode structures with high surface area to volume ratio, allowing significantly more charge storage sites while maintaining thin electrode profiles. The porous structure enables rapid ion access to internal surfaces, preserving fast response characteristics while increasing charge storage capacity by orders of magnitude compared to conventional parallel plate capacitors

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention transitions from conventional metal plate electrodes to composite porous electrodes incorporating conductive polymers and metal oxides. This parameter change in electrode composition and structure enables simultaneous achievement of high capacitance through increased surface area and fast response through improved ion transport kinetics in the porous network

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design significantly reduces the response time of the supercapacitor to microseconds, enabling high-power pulsed energy delivery with a simpler and less complex infrastructure compared to existing technologies.

Implementation Method 1

An explosion is a rapid release of stored chemical and/or mechanical energy. An explosion releasing stored chemical energy may result in the generation and release of gases at high pressure and/or temperature. The explosive will generate a compressive wavefront

Methodology Applied
Scientific EffectExplosion: Explosion

Implementation Method 2

In a supercapacitor, the flat metal plates are replaced by high surface area carbon or metal oxide materials, which increases the area by a factor of 1000 or more. Secondly, the charge on an electrode is now balanced by the formation of a charged layer within the liquid electrolyte that infuses throughout the electrode

Methodology Applied
Scientific EffectIon adsorption: Adsorption

Data Source

PatentUS11913759B2Energy dense source for pulse power applications and novel electromagnetic armor
Publication Date: 2024.02.27 BATTELLE MEMORIAL INST
  • US11913759B2 patent drawing
  • US11913759B2 patent drawing
  • US11913759B2 patent drawing

AI summary

A supercapacitor-like device is described that uses a porous, conductive foam as the electrodes. After the device is charged, an explosive wave front can be used to remove electrolyte from the metal foam. This creates a large net charge on each electrode, which will readily flow through a load placed across the electrodes. The removal of charge can potentially occur on a time scale of microseconds, allowing a supercapacitor to be used in pulsed power applications. The creation of this net charge requires significant energy, meaning this concept may also be suitable for removing kinetic energy from objects.