Exterior Low-E Coating Stack for Scratch-Resistant Anticondensation Glass

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Solution Overview

Problem

Existing anticondensation coatings for glass surfaces, such as skylights and vehicle windows, are either ineffective in preventing condensation or are energy inefficient and prone to scratches, with current solutions like pyrolytic fluorine-doped tin oxide coatings being unsuitable due to their durability and color change issues.

Innovation Solution

A thin-film anticondensation coating comprising layers of silicon nitride, transparent conductive oxide, and zirconium oxide, applied on the exterior surface of glass substrates, with a hemispherical emissivity of less than 0.23 and sheet resistance of less than 30 ohms/square, designed to retain heat and prevent condensation effectively.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If pyrolytic fluorine-doped tin oxide coating is applied to prevent condensation, then condensation prevention is achieved, but the coating scratches easily and changes color over time

Engineering Contradiction:
Improvecondensation preventionVSAvoidcoating durability
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies a composite coating structure consisting of multiple layers: a base coat layer, an intermediate layer, and a top coat layer. Each layer serves specific functions - the base coat provides adhesion and initial protection, the intermediate layer enhances durability and chemical resistance, and the top coat provides scratch resistance and color stability. This multi-layer composite approach resolves the contradiction by combining materials with complementary properties to achieve both condensation prevention and long-term durability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent implements different material compositions and properties at different layers of the coating system. Each layer is optimized for its specific function - the base coat for adhesion, the intermediate layer for chemical resistance and bonding, and the top coat for mechanical durability and aesthetic stability. This local differentiation of material qualities allows the overall system to achieve both condensation prevention and resistance to scratching and color change.

Inventive Principle:
Principle #3Local quality

2Reliability

If active heating elements are used to reduce condensation buildup, then condensation is reduced, but energy consumption increases and cost rises

Engineering Contradiction:
Improvecondensation reductionVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent creates a passive anticondensation coating system that functions without external energy input. The coating's hydrophilic properties cause water vapor to condense uniformly across the surface and drain away naturally through gravity, preventing localized fogging and droplet formation. This self-service mechanism eliminates the need for active heating elements, thereby reducing energy consumption while maintaining effective condensation control.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent replaces the mechanical/thermal system of active heating elements with a chemical/surface property-based passive coating system. Instead of using heat to prevent condensation, the coating modifies the surface energy characteristics to promote uniform water vapor distribution and natural drainage, substituting thermal energy input with surface chemistry engineering.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If thin-film anticondensation coating is applied to window surface, then condensation prevention is improved, but the coating is not durable in external environment

Engineering Contradiction:
Improvecondensation preventionVSAvoidcoating lifespan
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent employs a multi-layer composite coating system where each layer is specifically designed to address environmental challenges. The base coat provides strong adhesion to the glass substrate, the intermediate layer offers chemical resistance and mechanical reinforcement, and the top coat delivers environmental stability and durability. This composite structure enables the coating to maintain its anticondensation properties while withstanding external environmental stresses over extended periods.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent incorporates protective layers and material selections that anticipate and cushion against future environmental degradation. The intermediate and top coat layers are specifically engineered to protect the underlying functional layers from UV radiation, moisture, temperature fluctuations, and mechanical damage, thereby extending the overall coating lifespan while maintaining condensation prevention capabilities.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating significantly reduces or eliminates condensation on glass surfaces by retaining interior heat, improving durability, and maintaining aesthetic appeal while being energy efficient.

Implementation Method 1

a low hemispherical emissivity such that the glass surface is more likely to retain heat from the interior area

Methodology Applied
Scientific EffectThermal radiation: Thermal Radiation

Implementation Method 2

A thin-film anticondensation coating comprising layers of silicon nitride, transparent conductive oxide, and zirconium oxide, applied on the exterior surface of glass substrates

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS9199875B2Articles including anticondensation and/or low-E coatings and/or methods of making the same
Publication Date: 2015.12.01 GUARDIAN EURO S A R L
  • US9199875B2 patent drawing
  • US9199875B2 patent drawing
  • US9199875B2 patent drawing

AI summary

Certain example embodiments of this invention relate to articles including anticondensation and/or low-E coatings that are exposed to an external environment, and/or methods of making the same. In certain example embodiments, the anticondensation and/or low-E coatings may be survivable in an outside environment. The coatings also may have a sufficiently low sheet resistance and hemispherical emissivity such that the glass surface is more likely to retain heat from the interior area, thereby reducing (and sometimes completely eliminating) the presence condensation thereon. The articles of certain example embodiments may be, for example, skylights, vehicle windows or windshields, IG units, VIG units, refrigerator/freezer doors, and/or the like.