Extrudable Polymer Composition with Bicomponent Fibers

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Solution Overview

Problem

Molded articles made from polymers derived from renewable resources, such as polylactic acid (PLA), often exhibit brittleness and low impact strength due to non-optimum physical properties, limiting their use in various applications.

Innovation Solution

An extrudable polymer composition comprising a base polymer and bicomponent fibers with a low melt temperature component and a high melt temperature component, along with optional additives like natural oils, fatty acids, and nanofibers, is developed to enhance properties like heat deflection temperature, ductility, and barrier properties, mimicking those of petroleum-based polymers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If polymers derived from renewable resources (such as PLA) are used to make molded articles, then environmental sustainability is improved, but impact strength and toughness deteriorate

Engineering Contradiction:
Improveenvironmental sustainabilityVSAvoidimpact strength
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

The patent applies composite materials by combining PLA with impact modifiers such as polypropylene-glycidyl methacrylate (PP-g-EMA), polyethylene-glycidyl methacrylate (PE-g-EMA), and ethylene-methyl acrylate (EMA) copolymer. These impact modifiers are blended with PLA at specific ratios (e.g., 90:10 to 99:1 by weight) to create a composite material that maintains the biodegradability and sustainability of PLA while significantly improving impact strength and toughness through the synergistic effects of the modifier components.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If pure PLA is used for molded articles, then biodegradability is improved, but processability and heat resistance deteriorate

Engineering Contradiction:
ImprovebiodegradabilityVSAvoidprocessability
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent applies parameter changes by modifying the thermal and rheological properties of PLA through blending with impact modifiers that have different melting points and flow characteristics. The addition of modifiers such as PP-g-EMA (melting point ~160°C) and PE-g-EMA (melting point ~60°C) to PLA (melting point ~160-180°C) creates a multi-phase system with broadened processing temperature window, improved melt flow, and enhanced heat resistance while maintaining biodegradability of the primary PLA matrix.

Inventive Principle:
Principle #35Parameter changes

3Strength

If impact modifiers are added to PLA to improve toughness, then impact strength is improved, but material homogeneity deteriorates

Engineering Contradiction:
Improveimpact strengthVSAvoidmaterial homogeneity
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent applies the intermediary principle by using graft copolymers such as polypropylene-glycidyl methacrylate (PP-g-EMA) and polyethylene-glycidyl methacrylate (PE-g-EMA) as intermediary materials. These graft copolymers contain both the base polymer backbone (PP or PE) and functional groups (glycidyl methacrylate) that can interact with PLA through chemical or physical bonding. This intermediary structure facilitates compatibility between the hydrophobic PLA matrix and the impact modifier phases, improving dispersion and reducing phase separation while maintaining enhanced impact strength.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The extrudable polymer composition achieves improved physical properties, including higher heat deflection temperatures, impact resistance, and barrier properties, making it suitable for forming articles like containers and closures with enhanced performance.

Implementation Method 1

a bicomponent fiber comprising a low melt temperature component and a high melt temperature component

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentEP3280762B1Extrudable polymer composition and method of making molded articles utilizing the same
Publication Date: 2021.07.14 EARTH RENEWABLE TECH
  • EP3280762B1 patent drawingFigure 1
  • EP3280762B1 patent drawingFigure 2
  • EP3280762B1 patent drawingFigure 3

AI summary

The present invention provides an extrudable polymer composition comprising a base polymer and a bicomponent fiber comprising a low melt temperature component selected from the group consisting of high density polyethylene (HDPE) and polylactic acid (PLA) and a high melt temperature component selected from the group consisting of PET, 100% PDLA, 100% PLLA or a 50/50 blend of 100% PDLA and 100% PLLA, and nylon wherein the base polymer has a melt temperature of about 20°C to 40°C lower than this high melt temperature component of the bicomponent fiber.