Extruded Starch Sorbent Clumping via Water-Soluble Binder

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Solution Overview

Problem

Conventional clay-based cat litters are heavy, costly to ship, and difficult to handle due to high density, and their non-biodegradable nature complicates disposal, especially for environmental remediation applications.

Innovation Solution

An extruded granular sorbent formed from starch-containing materials with a water-soluble adhesive, which self-clumps when wetted, offering high clump retention and crush strength, and is biodegradable, reducing weight and environmental impact.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional clay-based absorbent materials are used, then absorbent performance is adequate, but weight and bulk density become excessive

Engineering Contradiction:
Improveabsorbent performanceVSAvoidbulk density
Core Design Contradiction:
Quantity of substanceVSWeight of moving object

Solution Approach 1:

The patent combines starch-based absorbent granules with a water-soluble adhesive binder to create a composite material that maintains absorbent performance while reducing bulk density. The starch granules provide absorption capability, while the adhesive binder enables clumping without requiring heavy clay components, achieving a bulk density below 640 kg/m³.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical composition parameters by replacing clay-based materials with starch-based materials and using a water-soluble adhesive binder. This parameter change transforms the material properties to achieve both adequate absorbent performance and reduced weight, with the binder solubilizing upon contact with moisture to facilitate clumping.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If clay-based sorbents are used for oil spill remediation, then absorption capacity is sufficient, but disposal becomes complicated and costly

Engineering Contradiction:
Improveabsorption capacityVSAvoiddisposal complexity
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The patent employs a biodegradable starch-based sorbent that can be disposed of through natural decomposition processes. Unlike clay-based sorbents requiring expensive high-temperature kiln treatment, the starch-based material breaks down naturally, eliminating the need for costly disposal infrastructure and reducing environmental impact.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent converts the previously harmful non-biodegradable nature of clay into a benefit by using biodegradable starch-based materials. The material's ability to decompose naturally transforms what would have been a disposal problem into an environmentally friendly solution, particularly for oil spill remediation where the sorbent can break down after use.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Weight of moving object

If lighter weight components are added to reduce bulk density, then weight decreases, but clumping performance deteriorates

Engineering Contradiction:
Improvebulk densityVSAvoidclumping performance
Core Design Contradiction:
Weight of moving objectVSReliability

Solution Approach 1:

The patent introduces a water-soluble adhesive binder as an intermediary substance that facilitates clumping between starch-based granules. This binder acts as a mediator that activates upon contact with moisture, creating strong adhesive bonds between granules to form stable clumps, thereby maintaining clumping performance while using lighter weight materials.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent incorporates the water-soluble adhesive binder into the granule structure during manufacturing, preparing it in advance to activate upon contact with moisture. This preliminary incorporation ensures that when the sorbent encounters liquid, the binder immediately solubilizes and provides clumping functionality, eliminating the need for heavy clay components.

Inventive Principle:
Principle #10Preliminary action

4Reliability

If starch-based materials with water-soluble adhesive are used, then clump retention rate improves, but manufacturing complexity increases

Engineering Contradiction:
Improveclump retention rateVSAvoidmanufacturing process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the absorbent granule material with the adhesive binder into a single integrated product during extrusion. By combining these functions into one manufacturing step rather than requiring separate application processes, the patent achieves high clump retention rates while avoiding excessive manufacturing complexity. The extrusion process simultaneously forms the granules and incorporates the binder.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The extruded granular sorbent achieves a clump retention rate of at least 93% and crush strength of 15 pounds per square inch, is lightweight, and biodegradable, making it easier to handle and dispose of, while minimizing dust and odor issues.

Implementation Method 1

water soluble adhesive formed from starches modified during extrusion sufficient to solubilize when wetted and at least become tacky enough to form clumps

Methodology Applied
Scientific EffectSolubilization: Solvation

Implementation Method 2

at least become tacky enough to form clumps having a relatively high clump retention rate and which possess high crush strength

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 3

wetted sorbent granules solubilize water-soluble binder in the extruded pellet of each wetted sorbent granule forming a flowable adhesive

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 4

The flowable adhesive rapidly increases in viscosity after wetting from a viscosity of at least 200 centipoise within one second after wetting, increases to at least 300 centipoise after one second and within five seconds after wetting

Methodology Applied
Scientific EffectViscosity increase:

Data Source

PatentEP4169376A1Extruded granular sorbent
Publication Date: 2023.04.26 PIONEER PET PRODUCTS LLC
  • EP4169376A1 patent drawingFigure 1
  • EP4169376A1 patent drawingFigure 2
  • EP4169376A1 patent drawingFigure 3

AI summary

Extruded granular sorbent formed of sorbent granules each being or including an extruded pellet containing water soluble binder sufficient to self-clump when wetted producing clumps of granules each having a clump retention rate of at least 90% and which shrink after clump formation during drying producing a nonstick clump that condenses pulling away from any contacting solid surface minimizing adhesion therebetween. Such clumps preferably also have a crush strength of at least 15 PSI when dry. Pellets preferably contain cold water-soluble amylopectin binder that not only solubilizes when wetted to facilitate clumping but which also opens the interior of the pellet improving absorption capacity. Sorbent well suited for use as litter is formed of granules or pellets having sizes falling within a plurality of different size ranges with the smaller sized fines causing the clumps to form on top of the litter extending generally horizontally along the litter.