Concentrated Laundry Detergent Using Fatty Acid Surfactants

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Solution Overview

Problem

Conventional laundry cleaning products contain petrochemical-based surfactants and chemicals that are not environmentally sustainable and pose acute oral toxicity risks, particularly due to the use of ethoxylated surfactants leading to 1,4-dioxane residues, a known carcinogen.

Innovation Solution

Development of concentrated laundry cleaning compositions using a synergistic blend of fatty acid-derived surfactants, enzymes, and enzyme stabilizers, including fatty alcohol ethoxylates, fatty acid methyl ester sulfonates, and fatty acid soaps, which are more environmentally friendly and safer for human and aquatic use, with a high renewable carbon index and low 1,4-dioxane content.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If ethoxylated surfactants are used in conventional laundry products, then cleaning performance is achieved, but 1,4-dioxane residues are formed which are carcinogenic and environmentally harmful

Engineering Contradiction:
Improvehuman and aquatic safetyVSAvoidcleaning performance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent removes ethoxylated surfactants from the formulation to eliminate 1,4-dioxane residues. Instead, it uses alternative surfactant systems including fatty acid methyl ester sulfonates (FAMES), alkyl polyglucosides (APG), and fatty acid soaps that do not produce carcinogenic byproducts, thereby extracting the harmful component while maintaining cleaning function through substitute ingredients.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical composition parameters by replacing petrochemical-based surfactants with bio-based alternatives. Specifically, it uses surfactants derived from renewable resources with different molecular structures that avoid dioxane formation, changing the fundamental chemical parameters of the formulation to achieve both safety and performance.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If petrochemical-based surfactants are used, then cleaning effectiveness is maintained, but environmental sustainability is compromised

Engineering Contradiction:
Improvecleaning effectivenessVSAvoidenvironmental impact
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent converts the limitation of bio-based surfactants (perceived as less effective) into an advantage by formulating synergistic combinations that enhance cleaning performance. It uses blends of FAMES, APG, fatty acid soaps, and enzymes that work together to achieve superior cleaning while providing biodegradability and environmental benefits, turning a perceived weakness into a strength.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent employs composite surfactant systems combining multiple bio-based ingredients (FAMES, APG, fatty acid soaps) with enzymes and builder chemicals. This composite approach creates a synergistic formulation where each component contributes specific functions, achieving comprehensive cleaning performance while maintaining environmental sustainability through biodegradability.

Inventive Principle:
Principle #40Composite materials

3Productivity

If concentrated formulations are used, then active ingredient efficiency is improved, but formulation stability and compatibility with packaging become more challenging

Engineering Contradiction:
Improveactive ingredient concentrationVSAvoidformulation stability
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent uses enzyme stabilizers and chelating agents as intermediary substances that protect the concentrated active ingredients from degradation. These intermediaries prevent unwanted reactions between surfactants and enzymes, maintain pH balance, and ensure compatibility with the packaging materials, enabling stable concentrated formulations.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes physical-chemical parameters including pH control, ionic strength, and surfactant concentration ratios to ensure stability in concentrated form. By carefully adjusting these parameters and using buffered systems, the formulation maintains stability while achieving high active ingredient concentration for improved productivity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides superior human and aquatic safety, improved detergency across water hardness levels, reduced environmental impact, and enhanced sustainability while maintaining performance, by utilizing a blend of fatty acid-derived surfactants and enzymes in a concentrated form that is more biodegradable and less toxic.

Implementation Method 1

a high performance synergistic blend of fatty acid derived surfactants and enzymes

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Implementation Method 2

one or more enzymes with enzyme stabilizers

Methodology Applied
Scientific EffectEnzyme catalysis: Enzyme

Implementation Method 3

fatty acid methyl ester sulfonate... can provide improved performance compared to commonly used dodecyl benzene sulfonates

Methodology Applied
Scientific EffectMicelle formation: Surfactant

Implementation Method 4

Additional surfactant performance and de-foaming in the wash can be accomplished with the use of a fatty acid based soap

Methodology Applied
Scientific EffectDe-foaming: Antifoam

Data Source

PatentUS12071599B2Concentrated laundry cleaning compositions in unit dose packets or pouches
Publication Date: 2024.08.27 KOREX CANADA CO

AI summary

An article includes a unit dose packet of a concentrated cleaning composition for cleaning laundry. The concentrated cleaning composition comprising a nonionic surfactant, fatty acid methyl ester sulfonate, fatty acid soap, one or a plurality of enzymes, and a solvent system. The cleaning composition is compatible with polyvinyl alcohol film. The unit dose packet includes the concentrated laundry cleaning composition disposed in a single chamber, dual chamber, or multi-chamber unit dose packet having a total weight of the concentrated cleaning composition of from 15 grams to 30 grams.