Fatty Acid Pyrolysis and Extraction for Pure Hydrocarbon Fuels

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Solution Overview

Problem

Traditional biodiesel production from fatty acids results in products that are susceptible to oxidation and have lower heating values than petroleum-based diesel, requiring blending and antioxidant supplementation to meet industry and regulatory standards, and often contains undesirable fatty acids that need removal for hydrocarbon solvent and fuel applications.

Innovation Solution

A method involving the pyrolysis of fatty acids to produce pure hydrocarbon compositions of alkanes and alkenes, followed by extraction to remove residual fatty acids, allowing for the reuse of removed fatty acids and reducing the need for high-temperature pyrolysis, thereby enhancing fuel and solvent production efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional trans-esterification method is used to produce biodiesel, then fuel production is achieved, but the product becomes susceptible to oxidation and has lower heating values requiring blending and antioxidants

Engineering Contradiction:
Improveoxidation resistanceVSAvoidprocessing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the chemical composition parameters of the fuel by using pyrolysis to convert fatty acids into hydrocarbons (alkanes and alkenes) rather than methyl esters. This fundamental parameter change in molecular structure eliminates the oxidation susceptibility inherent in traditional biodiesel while maintaining renewable fuel production.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If pyrolysis is used to produce hydrocarbons from fatty acids, then oxidation resistance is improved, but residual fatty acids remain that must be removed to meet standards

Engineering Contradiction:
Improveoxidation resistanceVSAvoidpurity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies extraction to remove residual fatty acids from the pyrolysis products. This separation process isolates the desired hydrocarbon components from unwanted fatty acid residues, achieving the purity required to meet industry and regulatory standards for fuels and solvents.

Inventive Principle:
Principle #2Taking out (Extraction)

3Manufacturing precision

If high-temperature pyrolysis is used to ensure complete conversion, then hydrocarbon purity is improved, but energy consumption increases

Engineering Contradiction:
Improvehydrocarbon purityVSAvoidenergy consumption
Core Design Contradiction:
Manufacturing precisionVSUse of energy by moving object

Solution Approach 1:

The patent uses moderate-temperature pyrolysis followed by extraction rather than high-temperature pyrolysis. This partial action approach achieves sufficient hydrocarbon conversion at lower temperatures, with the extraction step completing the purification process, thereby reducing overall energy consumption while maintaining product purity.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method produces high-purity hydrocarbons with reduced oxidation susceptibility and lower energy consumption, enabling the production of fuels and solvents that meet industry standards while allowing for the recycling of fatty acids, minimizing waste and energy use.

Implementation Method 1

The pyrolysis of fatty acids is one approach to producing the corresponding alkanes and alkenes useful as solvents and fuels

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Implementation Method 2

the pyrolysis products of fatty acids are extracted in order to remove residual fatty acids and produce very pure hydrocarbon compositions

Methodology Applied
Scientific EffectLiquid-liquid extraction: Liquid-Liquid Extraction

Data Source

PatentUS8975457B2Methods for producing fuels and solvents substantially free of fatty acids
Publication Date: 2015.03.10 FORGE HYDROCARBONS CORP
  • US8975457B2 patent drawing
  • US8975457B2 patent drawing
  • US8975457B2 patent drawing

AI summary

Described herein are methods for producing fuels and solvents from fatty acid resources. In general, the pyrolysis products of fatty acids are extracted in order to remove residual fatty acids and produce very pure hydrocarbon compositions composed of alkanes and alkenes. The fatty acids removed from the extraction step can be further pyrolyzed to produce additional hydrocarbons or, in the alternative, the fatty acids can be isolated and used in other applications. Also disclosed herein are fuels and solvents produced by the methods described herein.