Faujasite Molecular Sieves for TCA Removal in Wine

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Solution Overview

Problem

Current methods for removing 2,4,6 Trichloroanisole (TCA) from wine are inefficient, costly, and often alter the flavor and aroma profiles of the wine, with existing technologies requiring large quantities of treatment materials and having limited capacity for rapid taint removal.

Innovation Solution

The use of Zeolite-Y (Faujasite) molecular sieves with a silica-to-alumina ratio greater than 5, which selectively adsorb TCA from wine without significantly impacting desirable flavor and aroma components, allowing for rapid and economical remediation through direct incorporation into wine or packaging materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional TCA removal methods are used, then TCA taint is reduced, but large quantities of treatment material are required and costs increase

Engineering Contradiction:
ImproveTCA taintVSAvoidtreatment material quantity
Core Design Contradiction:
Object-affected harmful factorsVSQuantity of substance

Solution Approach 1:

The patent employs porous adsorbent materials with high surface area and selective pore structures to remove TCA from wine. These materials provide extensive adsorption capacity within a small volume, eliminating the need for large quantities of treatment material while effectively reducing TCA taint concentrations.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention utilizes adsorbents with optimized physical and chemical parameters including pore size distribution, surface area, and surface chemistry to achieve selective TCA adsorption. By changing the parameters of the adsorbent material, the system achieves high TCA removal efficiency with minimal material quantity required.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If conventional TCA removal methods are used, then TCA taint is reduced, but the flavor and aroma profiles of the wine are altered

Engineering Contradiction:
ImproveTCA taintVSAvoidflavor and aroma profile
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent applies adsorbent materials with locally optimized properties that provide high affinity for TCA molecules while having minimal interaction with wine flavor and aroma compounds. The selective adsorption capability is achieved through tailored pore structures and surface chemistries that discriminate between TCA and desirable wine components.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention transforms the harmful TCA compound into an adsorbed state on the porous material surface, effectively removing it from the wine. The process converts the taint problem into a beneficial adsorption phenomenon where TCA is selectively captured without affecting wine quality.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Object-affected harmful factors

If conventional TCA removal methods are used, then some TCA is removed, but the treatment process is slow and inefficient

Engineering Contradiction:
ImproveTCA concentrationVSAvoidtreatment speed
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent utilizes highly porous adsorbent materials with large surface areas and optimized pore structures that enable rapid mass transfer and fast adsorption kinetics. These materials provide numerous active sites for TCA molecules, dramatically increasing the treatment speed and productivity compared to conventional methods.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention may incorporate mechanical agitation or vibration during the adsorption process to enhance mass transfer rates and accelerate TCA removal. This mechanical energy input improves the kinetics of the adsorption process, enabling faster treatment while maintaining high removal efficiency.

Inventive Principle:
Principle #18Mechanical vibration

4Object-affected harmful factors

If conventional TCA removal methods are used, then TCA is removed from wine, but the treatment materials cannot be reused

Engineering Contradiction:
ImproveTCA removalVSAvoidtreatment material
Core Design Contradiction:
Object-affected harmful factorsVSLoss of substance

Solution Approach 1:

The patent implements a regeneration system where used adsorbent materials are recovered and regenerated for repeated use. The spent adsorbents can be thermally or chemically regenerated to restore their adsorption capacity, allowing multiple cycles of TCA removal and significantly reducing material loss and treatment costs.

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Faujasite molecular sieves effectively remove TCA from wine in seconds, achieving capacities orders of magnitude larger than existing technologies, with minimal impact on the wine's aroma and flavor profiles, and can be reused after regeneration.

Implementation Method 1

Zeolite-Y (Faujasite) molecular sieves with a silica-to-alumina ratio greater than 5, which selectively adsorb TCA from wine

Methodology Applied
Scientific EffectMolecular sieve: Molecular Sieve

Implementation Method 2

The use of Zeolite-Y (Faujasite) molecular sieves with a silica-to-alumina ratio greater than 5, which selectively adsorb TCA from wine

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS8057671B2Closure device capable of removing TCA in a beverage container
Publication Date: 2011.11.15 G3 ENTERPRISES
  • US8057671B2 patent drawing
  • US8057671B2 patent drawing
  • US8057671B2 patent drawing

AI summary

A means of preventing TCA taint from contaminating liquid foods and beverages is provided by incorporating molecular sieves into the manufacturing process and/or packaging materials in order to selectively adsorb the taint molecules while preserving the food's or beverage's flavor and aroma profiles. Also provided are methods and devices for remediating TCA taint present in the consumer's liquid foods and beverages.