FCC Riser Vent Tubes for Catalyst Separation

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Solution Overview

Problem

In Fluidic Catalytic Cracker (FCC) reactors, unwanted thermal and catalytic reactions occur due to inefficient separation of hydrocarbon vapors and catalysts, leading to reduced hydrocarbon yields and catalyst fouling, primarily caused by hydrocarbon underflow and recirculation in separation systems.

Innovation Solution

The solution involves lowering the catalyst bed level in the separation system to minimize contact time between hydrocarbon vapors and catalysts, using vent tubes to bypass hydrocarbon vapors and prevent remixing, and optimizing catalyst inventory to reduce entrainment and underflow, thereby enhancing separation efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the catalyst bed level is lowered in the separation system, then hydrocarbon vapor separation efficiency is improved and unwanted reactions are reduced, but catalyst inventory is decreased which may affect reaction capacity

Engineering Contradiction:
Improvehydrocarbon yieldVSAvoidcatalyst inventory
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The separation system is divided into distinct zones: an upper vapor outlet zone and a lower catalyst bed zone. The catalyst bed is positioned at a lower level with vent tubes extending upward, creating spatial segmentation that allows vapor to be separated from catalyst while maintaining catalyst inventory in the lower zone. This segmentation resolves the contradiction by enabling efficient separation without requiring excessive catalyst inventory throughout the entire separation space.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Vent tubes are extended vertically upward from the lower catalyst bed into the upper vapor zone, adding a vertical dimension to the separation process. This dimensional approach allows vapor to rise through the vent tubes and be separated from the catalyst bed, improving separation efficiency while maintaining catalyst inventory in the lower zone rather than requiring catalyst throughout the entire volume.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Object-affected harmful factors

If catalyst and hydrocarbon vapor contact time is reduced, then unwanted thermal and catalytic reactions are minimized, but separation efficiency may be compromised

Engineering Contradiction:
Improveunwanted reactionsVSAvoidseparation efficiency
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

Vent tubes serve as an intermediary structure between the catalyst bed and the vapor outlet. Vapor rises through these tubes, which are positioned above the catalyst bed level, allowing separation without direct prolonged contact. This intermediary approach minimizes unwanted reactions by reducing contact time while maintaining separation efficiency through the structured vent tube pathway.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-generated harmful factors

If hydrocarbon underflow is prevented, then catalyst fouling is reduced and yield selectivity is improved, but separation system complexity increases

Engineering Contradiction:
Improvecatalyst foulingVSAvoidseparation system structure
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The catalyst bed is positioned at a lower level before the vapor outlet, and vent tubes are pre-positioned to extend upward from this lower bed. This preliminary positioning prevents hydrocarbon underflow from occurring in the first place, rather than requiring complex active control systems. The geometry itself preemptively prevents the harmful underflow phenomenon, reducing catalyst fouling without adding operational complexity.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces unwanted reactions, increases hydrocarbon yields, decreases catalyst fouling, and lowers energy consumption by minimizing hydrocarbon underflow and recirculation, resulting in more efficient FCC operations with improved product recovery and reduced regenerator temperatures.

Implementation Method 1

Gases leave the reactor through the cyclones after separation from the powdered catalyst

Methodology Applied
Scientific EffectCyclone separation: Cyclone Separation

Implementation Method 2

The riser creates a fluidized bed where a concurrent upward flow of reactant gases and catalyst particles occurs

Methodology Applied
Scientific EffectFluidization: Fluidisation

Implementation Method 3

The spent catalyst is commonly sent to a regenerator unit and is regenerated by combusting carbon deposits to carbon dioxide

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentUS11542441B2FCC yield selectivity improvements in high containment riser termination systems
Publication Date: 2023.01.03 MARATHON PETROLEUM COMPANY LP
  • US11542441B2 patent drawing
  • US11542441B2 patent drawing
  • US11542441B2 patent drawing

AI summary

The invention provides an improved system for separation technology intended to reduce unwanted catalyst/thermal reactions by minimizing contact of the hydrocarbons and the catalyst within the reactor.