Fe-based Soft Magnetic Thin Strip with Fine Crystalline Grains

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Solution Overview

Problem

Current soft magnetic materials face challenges such as high core loss in high-frequency applications, low saturation magnetic flux density, thermal instability, and high cost due to Co content, along with issues like high noise and magnetostriction, which limit their effectiveness in high-power applications.

Innovation Solution

A soft magnetic thin ribbon with a composition of Fe-based alloy containing elements like Cu, Ti, Zr, and P, produced through rapid cooling and high-temperature annealing, resulting in fine crystalline grains dispersed in an amorphous phase, achieving a saturation magnetic flux density of not lower than 1.7 T and low coercive force.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If Fe-based amorphous soft magnetic alloy is used, then soft magnetic properties are improved, but saturation magnetic flux density is limited to about 1.65 T

Engineering Contradiction:
Improvesoft magnetic propertiesVSAvoidsaturation magnetic flux density
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The invention changes the fundamental structural parameter from amorphous to fine crystalline with grain size of 10 nm to 100 nm. This parameter change enables the material to achieve saturation magnetic flux density of 1.7 T or higher while maintaining excellent soft magnetic properties, overcoming the 1.65 T limit of conventional amorphous alloys

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite structure consisting of fine crystalline grains dispersed in an amorphous matrix. This composite architecture combines the advantages of both crystalline (high saturation flux density) and amorphous (excellent soft magnetic properties) phases, achieving performance that neither phase can provide alone

Inventive Principle:
Principle #40Composite materials

2Reliability

If Fe-based amorphous soft magnetic alloy is used, then coercive force is reduced, but magnetostriction increases causing high noise

Engineering Contradiction:
Improvecoercive forceVSAvoidnoise
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention changes the grain size parameter to the nano-scale range (10-100 nm), which fundamentally alters the magnetic domain structure. This enables the material to exhibit both low coercive force and low magnetostriction, eliminating the trade-off present in conventional materials

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates local crystalline regions with specific grain size characteristics within the amorphous matrix. These localized fine crystalline structures provide low magnetostriction properties while the overall composite structure maintains low coercive force, resolving the contradiction between these two properties

Inventive Principle:
Principle #3Local quality

3Quantity of substance

If Co-based amorphous alloy is used, then saturation magnetic flux density is achieved, but thermal instability occurs

Engineering Contradiction:
Improvesaturation magnetic flux densityVSAvoidthermal instability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The invention replaces expensive and thermally unstable Co-based amorphous alloys with a Fe-based fine crystalline alloy. The Fe-based composition is inherently more thermally stable and cost-effective, while the fine crystalline structure maintains high saturation magnetic flux density of 1.7 T or higher

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The fine crystalline-amorphous composite structure provides thermal stability through the amorphous matrix while the dispersed fine crystalline grains maintain high magnetic performance. This composite approach eliminates the thermal instability inherent in Co-based amorphous alloys

Inventive Principle:
Principle #40Composite materials

4Quantity of substance

If silicon steel plate is used, then magnetic flux density is high, but core loss increases in high-frequency applications

Engineering Contradiction:
Improvemagnetic flux densityVSAvoidcore loss
Core Design Contradiction:
Quantity of substanceVSLoss of energy

Solution Approach 1:

The invention changes the material structure from conventional crystalline silicon steel to fine crystalline with 10-100 nm grain size. This dramatic reduction in grain size reduces eddy current paths and magnetic domain wall movement losses, thereby reducing core loss in high-frequency applications while maintaining high magnetic flux density

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The fine crystalline structure with grain sizes in the 10-100 nm range creates a microstructure that effectively reduces eddy currents. The thin crystalline regions act as natural insulation barriers, reducing energy loss in high-frequency applications compared to conventional thick-grained silicon steel

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a cost-effective, high-performance soft magnetic material with improved toughness, low hysteresis loss, and reduced noise, suitable for high-power applications, including transformers, reactors, and noise suppression parts.

Implementation Method 1

produced through rapid cooling and high-temperature annealing

Methodology Applied
Scientific EffectRapid cooling: Cooling

Implementation Method 2

resulting in fine crystalline grains dispersed in an amorphous phase

Methodology Applied
Scientific EffectAmorphous phase formation: Vitrification

Implementation Method 3

produced through rapid cooling and high-temperature annealing

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 4

resulting in fine crystalline grains dispersed in an amorphous phase

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentEP2149616B1Soft magnetic thin strip, process for production of the same, magnetic parts, and amorphous thin strip
Publication Date: 2017.01.11 PROTERIAL LTD
  • EP2149616B1 patent drawing
  • EP2149616B1 patent drawing
  • EP2149616B1 patent drawing

AI summary

The invention provides a soft magnetic thin strip which contains nanoscale fine grains and exhibits a high saturation magnetic flux density and excellent soft magnetic characteristics; a process for production of the same; magnetic parts; and an amorphous thin strip to be used in the production. In the invention, an amorphous thin strip is used, which is represented by the composition formula: Fe100-x-y-zAxMyXz-aPa (wherein A is at least one element selected from between Cu and Au; M is at least one element selected from among Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W and Mn; X is at least one element selected from between B and Si; and x, y, z and a (in terms of atomic percentage) satisfy the relationships: 0.5 ≦ x ≦ 1.5, 0 ≦ y ≦ 2.5, 10 ≦ z ≦ 23, and 0.35 ≦ a ≦ 10 respectively) and permits 180° bending. The amorphous thin strip can give through anneal a soft magnetic thin strip having a structure wherein grains of body-centered cubic structure having an average grain size of 60nm or below are distributed in an amorphous phase with a grain volume fraction of 30% or above.