Fe/GaN Thin Films for Stable MRAM Data Retention

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Solution Overview

Problem

Current magnetic random-access memory (MRAM) devices face challenges in achieving stable data retention due to limited perpendicular magnetic anisotropy (PMA) that is insufficient to withstand thermal fluctuations, limiting storage density and retention time.

Innovation Solution

Giant perpendicular magnetic anisotropy is achieved by growing Fe ultrathin films on a nitrogen-terminated surface, specifically on wurtzite GaN substrates, utilizing a monolayer of nitrogen and iron films, which enhances the spin-orbit coupling and on-site electron-electron correlation interactions to increase PMA by one order of magnitude.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional magnetic thin films are used, then device structure is simple, but perpendicular magnetic anisotropy is insufficient to withstand thermal fluctuations

Engineering Contradiction:
Improvedata retention stabilityVSAvoidfilm structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs a composite thin film structure consisting of multiple layers including CoFeB, MgO, and Ta layers. This composite structure generates perpendicular magnetic anisotropy through interfacial effects between different materials, achieving stable data retention against thermal fluctuations while maintaining a manageable device structure.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes critical parameters such as film thickness (e.g., CoFeB layer thickness of 3-5 nm, MgO layer thickness of 1-3 nm) and composition ratios to achieve the desired perpendicular magnetic anisotropy. By precisely controlling these parameters, the system achieves enhanced reliability without excessive structural complexity.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If magnetic domain size is reduced to increase storage density, then storage density improves, but magnetic anisotropy stability against thermal fluctuations deteriorates

Engineering Contradiction:
Improvestorage densityVSAvoidmagnetic anisotropy stability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The composite CoFeB/MgO/Ta thin film structure provides strong perpendicular magnetic anisotropy that stabilizes magnetic domains even at reduced sizes. The interfacial effects in this composite system enhance the magnetic anisotropy energy, allowing smaller magnetic domains to maintain stability against thermal fluctuations while enabling higher storage density.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes interfacial effects at specific locations within the thin film structure (particularly at the CoFeB/MgO and MgO/Ta interfaces) to generate perpendicular magnetic anisotropy. This localized enhancement of magnetic properties at critical interfaces allows small magnetic domains to achieve the necessary stability without requiring large overall domain sizes.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in unprecedented PMA values, enabling ultra-high storage density and 10-year data retention at room temperature, suitable for next-generation data storage devices like spin transfer torque-MRAM.

Implementation Method 1

utilizing a monolayer of nitrogen and iron films, which enhances the spin-orbit coupling and on-site electron-electron correlation interactions to increase PMA by one order of magnitude

Methodology Applied
Scientific EffectSpin-orbit coupling:

Implementation Method 2

Giant perpendicular magnetic anisotropy is achieved by growing Fe ultrathin films on a nitrogen-terminated surface

Methodology Applied
Scientific EffectPerpendicular magnetic anisotropy:

Data Source

PatentUS11031167B2Giant perpendicular magnetic anisotropy in Fe/GaN thin films for data storage and memory devices
Publication Date: 2021.06.08 UNIVERSITY OF NEW HAMPSHIRE
  • US11031167B2 patent drawing
  • US11031167B2 patent drawing
  • US11031167B2 patent drawing

AI summary

A giant perpendicular magnetic anisotropy (PMA) material comprises a III-V nitride substrate, and a layer of nitrogen disposed upon a surface of the III-V nitride substrate. The layer of nitrogen forms an N-terminated surface. The PMA material further comprises an iron film disposed upon the N-terminated surface. The III-V nitride substrate may be gallium nitride (GaN). A memory device using the PMA material may further comprise an input/output interface configured to communicate an address signal, a read/write signal and a data signal. The memory device may further comprise a controller configured to coordinate reading data from and writing data to the memory element.