FeRAM Capping Structure for Reducing Interface Oxygen Vacancies

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Solution Overview

Problem

Ferroelectric random-access memory (FeRAM) devices face defects such as oxygen vacancies and surface states at the interface between the active structure and the gate dielectric layer, which reduce charge mobility and affect switching speeds and reliability.

Innovation Solution

A capping structure comprising a first metal oxide material with high bonding energy is formed over the active structure, and a cocktail layer with a mixture of metal oxides is used at the interface to reduce defects, while a second metal layer with strong oxidation ability is used to oxidize weakly bonded oxygen, enhancing charge mobility.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional interface structure is used between active structure and gate dielectric layer, then device structure is simple, but oxygen vacancies and surface states increase, reducing charge mobility

Engineering Contradiction:
Improvecharge mobilityVSAvoidinterface structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The interface between active structure and gate dielectric layer is segmented into multiple distinct layers: a first interface layer with high bonding energy to reduce oxygen vacancies, a second interface layer to passivate surface states, and a third interface layer to provide structural stability. This segmentation allows each layer to address specific defect mechanisms independently, improving charge mobility without creating excessive overall complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first interface layer acts as an intermediary between the active structure and gate dielectric layer, using materials with high bonding energy to capture and reduce oxygen vacancies. This intermediary layer prevents direct contact between the active structure and gate dielectric, thereby reducing interface defects and improving charge mobility while maintaining structural integrity.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If interface defects are reduced through material optimization, then charge mobility improves, but manufacturing process complexity increases

Engineering Contradiction:
Improveswitching speedVSAvoidinterface fabrication ease
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention changes material parameters by selecting specific materials with high bonding energy for the first interface layer and specific band gap characteristics for the second interface layer. These parameter changes are implemented through standard thin-film deposition techniques, allowing defect reduction and improved switching speed without requiring fundamentally new manufacturing processes.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If a capping structure with high bonding energy material is used, then oxygen vacancies are reduced and charge mobility increases, but device structure becomes more complex

Engineering Contradiction:
Improvecharge mobilityVSAvoidcapping structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The capping structure implements local quality by applying materials with high bonding energy specifically at the interface region where oxygen vacancies are most problematic, rather than uniformly throughout the entire device. This localized approach reduces oxygen vacancies and improves charge mobility while minimizing overall structural complexity.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution increases charge mobility and reduces defects, leading to improved switching speeds and reliability of the FeRAM device by minimizing oxygen vacancies and surface states.

Implementation Method 1

a second metal layer with strong oxidation ability is used to oxidize weakly bonded oxygen, enhancing charge mobility

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS12114507B2Capping layer over FET FeRAM to increase charge mobility
Publication Date: 2024.10.08 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US12114507B2 patent drawing
  • US12114507B2 patent drawing
  • US12114507B2 patent drawing

AI summary

In some embodiments, the present disclosure relates to an integrated chip that includes a gate electrode over a substrate, and a gate dielectric layer arranged over the gate electrode. The gate dielectric layer includes a ferroelectric material. An active structure is arranged over the gate dielectric layer and includes a semiconductor material. A source contact and a drain contact are arranged over the active structure. A capping structure is arranged between the source and drain contacts and over the active structure. The capping structure includes a first metal material.