Metallizing Ferrite Ceramics via Copper Melting

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Solution Overview

Problem

Current metallization processes for ferrite ceramics are environmentally unfriendly and costly due to high water consumption and the use of silver, which also compromise the magnetic properties of the ceramic when using reduced oxygen atmospheres.

Innovation Solution

A process involving the simple melting of a copper or copper alloy contact element on the ferrite ceramic surface, forming a transition layer of copper and copper oxide for reliable bonding, eliminating the need for thick film pastes and electrochemical processes, and allowing for environmentally friendly joining without additional force.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If silver paste with thick film coating and baking is used for metallization, then reliable bonding is achieved, but water consumption increases and environmental harm occurs

Engineering Contradiction:
Improvebonding reliabilityVSAvoidenvironmental harm
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The invention extracts and eliminates the harmful elements (silver paste, thick film coating, baking process, electrochemical processes) from the metallization process while retaining the essential function of creating reliable electrical connections on ferrite ceramic surfaces

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the metallization approach from chemical/electrochemical processes to a physical vapor deposition or plasma process, fundamentally altering the process parameters to eliminate water consumption and chemical waste while maintaining bonding reliability

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If copper paste is used instead of silver paste, then cost is reduced, but oxidation occurs requiring reduced oxygen atmosphere

Engineering Contradiction:
Improvematerial costVSAvoidprocess complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The invention uses copper or copper alloy contact elements that are cost-effective compared to silver, accepting their shorter operational lifespan in exchange for significant cost reduction while managing oxidation through controlled atmosphere processing

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention employs a controlled atmosphere (reduced oxygen content) during the heating process to prevent copper oxidation, creating a temporary inert environment that allows cost-effective copper metallization without the complexity of additional protective coatings

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

3Object-affected harmful factors

If reduced oxygen atmosphere is used for copper metallization, then oxidation is prevented, but magnetic properties of ferrite ceramic are adversely affected

Engineering Contradiction:
Improveoxidation preventionVSAvoidmagnetic properties
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The invention applies a protective coating to the ferrite ceramic surface before copper metallization, creating a barrier that allows reduced oxygen atmosphere processing without affecting the magnetic properties of the ceramic bulk

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention introduces an intermediary protective layer between the ferrite ceramic and the copper contact element, which mediates the interaction during heating by preventing direct oxidation while allowing the magnetic properties of the ceramic to remain stable

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method provides reliable and cost-effective metallization with reduced environmental impact, preserving the magnetic properties of the ferrite ceramic and enabling direct soldering, while avoiding the use of silver and harsh chemical processes.

Implementation Method 1

melting of the contact element at least in the region in which the contact element contacts the surface of the ferrite ceramic

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

heating is carried out in such a way that no liquid phases occur

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

cooling of the contact element and the ferrite ceramic to below the melting point of copper or the copper alloy

Methodology Applied
Scientific EffectCooling: Cooling

Data Source

PatentUS11236024B2Method of metallizing ferrite ceramics and component comprising a metallized ferrite ceramic
Publication Date: 2022.02.01 WURTH ELEKTRONIK EISOS
  • US11236024B2 patent drawing

AI summary

The invention relates to a process for metallizing ferrite ceramics, which comprises the following steps: arrangement of a contact element composed of copper or a copper alloy on a surface of the ferrite ceramic, melting of the contact element at least in the region in which the contact element contacts the surface of the ferrite ceramic, and cooling of the contact element and the ferrite ceramic to below the melting point of copper or the copper alloy.