Ferritic Stainless Steel Pipe-End Structure for Crevice Salt Corrosion

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Solution Overview

Problem

Existing ferritic stainless steel pipes with thickened ends lack effective corrosion resistance in crevice environments, leading to potential perforation and leakage due to salt damage corrosion, which is not adequately addressed by existing techniques.

Innovation Solution

A ferritic stainless steel pipe composition with specific elements (C, Si, Mn, P, S, Cr, Sn, Ti, Al, and N) and a pipe-end-thickened structure where the gap distance satisfies the relationship d≥Cr2/(1000 Sn), enhancing corrosion resistance against salt damage in crevice portions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If pipe end is thickened to increase strength and rigidity, then welded portion strength is improved, but crevice corrosion resistance deteriorates due to gap structure formation

Engineering Contradiction:
Improvewelded portion strengthVSAvoidcrevice corrosion resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention applies different material compositions to different regions of the pipe. The base pipe uses standard ferritic stainless steel composition, while the pipe end portion (thickened portion) uses a specially optimized composition with higher Cr (14-20 mass%) and Sn (0.01-1.0 mass%) content to specifically address crevice corrosion resistance in the gap structure region, thus resolving the contradiction between strength enhancement and corrosion resistance deterioration.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention changes the chemical composition parameters of the pipe end portion material. By increasing Cr content to 14-20 mass% and Sn content to 0.01-1.0 mass%, and controlling the gap distance d to satisfy d≥Cr2/(1000 Sn), the material parameters are optimized to provide excellent crevice corrosion resistance while maintaining the thickened structure for strength.

Inventive Principle:
Principle #35Parameter changes

2Weight of moving object

If pipe end is thickened to reduce overall system weight, then non-welded portions can be made thinner, but salt damage corrosion resistance in crevice portion deteriorates

Engineering Contradiction:
Improveoverall system weightVSAvoidsalt damage corrosion resistance
Core Design Contradiction:
Weight of moving objectVSObject-affected harmful factors

Solution Approach 1:

The invention applies a specialized material composition specifically to the pipe end portion where the crevice structure forms. The base pipe can use thinner walls for weight reduction, while the thickened pipe end uses a material with optimized Cr (14-20 mass%) and Sn (0.01-1.0 mass%) content to provide localized protection against salt damage corrosion in the gap structure, thus resolving the contradiction between weight reduction and corrosion resistance.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention effectively creates a composite structure where the pipe consists of different material compositions in different regions. The base pipe material and the pipe end portion material have different chemical compositions optimized for their respective functions, with the pipe end portion having enhanced Cr and Sn content to resist salt damage corrosion while enabling overall system weight reduction.

Inventive Principle:
Principle #40Composite materials

3Reliability

If gap distance is reduced to minimize crevice structure, then corrosion resistance should improve, but manufacturing precision becomes difficult to control

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidgap distance control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

Instead of simply minimizing the gap distance, the invention changes the approach by establishing a mathematical relationship d≥Cr2/(1000 Sn) that connects the gap distance to the material composition parameters (Cr and Sn content). This allows the gap distance to be controlled within a reasonable range (several micrometers to several hundreds of micrometers) while maintaining excellent corrosion resistance through optimized material composition, thus resolving the contradiction between corrosion resistance and manufacturing precision.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS11215299B2Ferritic stainless steel pipe having excellent salt tolerance in gap, pipe-end-thickened structure, welding joint, and welded structure
Publication Date: 2022.01.04 NIPPON STEEL STAINLESS STEEL CORP
  • US11215299B2 patent drawing
  • US11215299B2 patent drawing
  • US11215299B2 patent drawing

AI summary

This ferritic stainless steel pipe contains, by mass %: C: 0.001% to 0.100%; Si: 0.01% to 2.00%; Mn: 0.01% to 2.00%; P: 0.001% to 0.05%; S: 0.0001% to 0.005%; Cr: 10.5% to 20.0%; Sn: 0.001% to 0.600%; Ti: 0.001% to 1.000%; Al: 0.001% to 0.100%; and N: 0.001% to 0.02%, with a balance being Fe and unavoidable impurities, the ferritic stainless steel pipe includes a pipe-end-thickened portion at a pipe end portion, and a gap distance d (μm) formed at the pipe end portion satisfies a relationship of d≥Cr2/(1000Sn) (in the expression, Cr and Sn represent amounts (mass %) of respective elements).