Ferritic Stainless Steel Interconnect Silica Layer Reduction

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Solution Overview

Problem

Ferritic stainless steel interconnects in SOFCs form electrically resistive silica layers due to silicon migration, leading to increased contact resistivity and reduced fuel cell efficiency over time.

Innovation Solution

A method involving pre-oxidizing silicon-containing ferritic stainless steel articles in an oxidizing atmosphere to form a silica layer, which is then partially or fully removed, depleting silicon from the near-surface region to inhibit further silica formation during high-temperature oxidizing conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If ferritic stainless steel interconnects are used in SOFCs, then cost and manufacturability are improved, but electrically resistive silica layers form on the surface leading to increased contact resistivity

Engineering Contradiction:
ImprovemanufacturabilityVSAvoidcontact resistivity
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies preliminary action by performing a pre-oxidation treatment during manufacturing to deliberately form and remove silica layers before the interconnect is put into service. This preliminary removal of silicon-rich surface layers prevents the formation of electrically resistive silica during subsequent fuel cell operation, thereby maintaining low contact resistivity while preserving the manufacturability benefits of ferritic stainless steel.

Inventive Principle:
Principle #10Preliminary action

2Quantity of substance

If silicon-containing ferritic stainless steel is used, then material availability and cost are improved, but silicon migration to the surface forms electrically resistive layers

Engineering Contradiction:
Improvesilicon contentVSAvoidsilica layer formation
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent converts the harmful effect of silicon migration into a beneficial outcome by utilizing the pre-oxidation treatment to deliberately form silica layers that are then removed. This process depletes silicon from the near-surface region, transforming the originally harmful silicon migration tendency into a controlled manufacturing step that prevents future silica formation and maintains electrical conductivity.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Reliability

If high-temperature oxidizing conditions are applied during pre-treatment, then silicon is depleted from the surface, but additional processing steps are required

Engineering Contradiction:
Improveelectrical conductivityVSAvoidprocessing steps
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the pre-oxidation treatment with existing manufacturing processes such as annealing or scale formation steps that are already part of the ferritic stainless steel production workflow. By combining the silicon-depleting pre-oxidation with these existing thermal processing steps, the patent reduces the need for additional separate processing operations while achieving the desired surface modification for low contact resistivity.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Significantly reduces the area-specific resistivity of ferritic stainless steel interconnects, enhancing electrical conductivity and extending the service life of fuel cells by minimizing silica layer growth.

Implementation Method 1

subjecting the steel to oxidizing conditions under which silica including silicon derived from the steel forms on a surface of the steel

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

form electrically resistive silica layers due to silicon migration

Methodology Applied
Scientific EffectSilicon migration: Diffusion

Data Source

PatentUS9580789B2Method for reducing formation of electrically resistive layer on ferritic stainless steels
Publication Date: 2017.02.28 ATI PROPERTIES INC
  • US9580789B2 patent drawing
  • US9580789B2 patent drawing
  • US9580789B2 patent drawing

AI summary

A method of reducing the formation of electrically resistive scale on a an article comprising a silicon-containing ferritic stainless subjected to oxidizing conditions in service includes, prior to placing the article in service, subjecting the article to conditions under which silica, which includes silicon derived from the steel, forms on a surface of the steel. Optionally, at least a portion of the silica is removed from the surface to placing the article in service. A ferritic stainless steel alloy having a reduced tendency to form silica on at least a surface thereof also is provided. The steel includes a near-surface region that has been depleted of silicon relative to a remainder of the steel.