Ferro Coke Carbonization Temperature Optimization

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Solution Overview

Problem

Current methods for manufacturing ferrocoke do not optimize CO2 reactivity of coke in blast furnaces, leading to high reducing agent ratios and thermal reserve zone temperatures, despite the catalytic effect of reduced iron ore.

Innovation Solution

A metallurgical ferrocoke manufacturing method involving briquetting a carbonaceous material and iron ore, with carbonization temperatures between 800°C and 900°C, and a ferrocoke particle diameter of 15 mm to 28 mm, using a vertical furnace with a specific gas composition to enhance CO2 reactivity and reduce thermal reserve zone temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If carbonization temperature is decreased to improve CO2 reactivity of coke, then CO2 reactivity is improved, but thermal reserve zone temperature in blast furnace increases

Engineering Contradiction:
ImproveCO2 reactivity of cokeVSAvoidthermal reserve zone temperature
Core Design Contradiction:
Measurement precisionVSTemperature

Solution Approach 1:

The invention changes the carbonization temperature parameter to a specific range (800-900°C) that optimizes both CO2 reactivity and thermal reserve zone temperature. This parameter optimization resolves the contradiction by finding the optimal point where CO2 reactivity is sufficiently high while thermal reserve zone temperature is maintained at acceptable levels.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite material consisting of carbonaceous material and iron ore mixed together before carbonization. The iron ore component (5-40 mass%) provides catalytic effect that enhances CO2 reactivity of the coke, allowing the system to achieve high reactivity without excessively lowering carbonization temperature, thus resolving the contradiction between reactivity and thermal reserve zone temperature.

Inventive Principle:
Principle #40Composite materials

2Measurement precision

If carbonization temperature is decreased to increase CO2 reactivity, then CO2 reactivity increases, but reducing agent ratio in blast furnace increases

Engineering Contradiction:
ImproveCO2 reactivity of cokeVSAvoidreducing agent ratio
Core Design Contradiction:
Measurement precisionVSQuantity of substance

Solution Approach 1:

By optimizing the carbonization temperature to 800-900°C, the invention achieves high CO2 reactivity without excessively lowering the temperature, thereby avoiding the need to increase reducing agent ratio. This parameter optimization directly resolves the contradiction between CO2 reactivity and reducing agent ratio.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite material of carbonaceous material and iron ore creates coke with enhanced CO2 reactivity through catalytic effect of reduced iron ore. This allows the blast furnace to achieve efficient reduction reactions with lower reducing agent ratio, resolving the contradiction between reactivity and reducing agent quantity.

Inventive Principle:
Principle #40Composite materials

3Measurement precision

If iron ore content is increased to enhance catalytic effect, then CO2 reactivity increases, but manufacturing cost and complexity increase

Engineering Contradiction:
ImproveCO2 reactivity of cokeVSAvoidmanufacturing process complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The invention optimizes the iron ore content parameter to a specific range (5-40 mass%) that provides sufficient catalytic effect for high CO2 reactivity while avoiding excessive complexity in the manufacturing process. This parameter optimization resolves the contradiction between reactivity enhancement and manufacturing simplicity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively increases CO2 reactivity of ferrocoke, decreasing the reducing agent ratio in blast furnaces while maintaining a necessary carbonization temperature, thus contributing to heat adjustment and improved blast furnace operations.

Implementation Method 1

carbonizing the briquette

Methodology Applied
Scientific EffectCarbonization: Pyrolysis

Implementation Method 2

CO 2 reactivity of coke in ferrocoke due to a catalytic effect of reduced iron ore

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

a furnace top gas of the vertical furnace is used as a gas that heats up the briquette

Methodology Applied
Scientific EffectConvection heating: Convection

Data Source

PatentEP2543716B1Process for producing ferro coke for metallurgy
Publication Date: 2019.04.03 JFE STEEL CORP
  • EP2543716B1 patent drawingFigure 1~2
  • EP2543716B1 patent drawingFigure 3~4
  • EP2543716B1 patent drawingFigure 5~6

AI summary

An object of the present invention is to provide a method of manufacturing ferrocoke by which CO2 reactivity of coke in ferrocoke in a blast furnace is increased thereby decreasing a thermal reserve zone temperature and decreasing a reducing agent ratio when a briquette including a carbonaceous material and iron ore is carbonized to manufacture ferrocoke. The present invention is a metallurgical ferrocoke manufacturing method of manufacturing ferrocoke by carbonizing a mixture of a carbonaceous material and iron ore and is characterized in that a maximum temperature of ferrocoke during the carbonization is in a range of 800°C or higher and 900°C or lower.